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Thermodynamic properties of ammonium haloplatinates: II. Heat capacity and thermodynamic functions of deuterated ammonium hexachloroplatinate (ND4)2PtCl6 at temperatures from 5 K to 350 K
dc.contributor.authorWeir, Ron D.en_US
dc.contributor.authorWestrum, Jr. , Edgar F.en_US
dc.date.accessioned2006-04-10T14:40:41Z
dc.date.available2006-04-10T14:40:41Z
dc.date.issued1991-07en_US
dc.identifier.citationWeir, Ron D., Westrum, Jr., Edgar F. (1991/07)."Thermodynamic properties of ammonium haloplatinates: II. Heat capacity and thermodynamic functions of deuterated ammonium hexachloroplatinate (ND4)2PtCl6 at temperatures from 5 K to 350 K." The Journal of Chemical Thermodynamics 23(7): 653-665. <http://hdl.handle.net/2027.42/29263>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WHM-4H3BC7X-6/2/5e6bbd1c88d4f756aa5c0b0e96c5ae4fen_US
dc.identifier.urihttps://hdl.handle.net/2027.42/29263
dc.description.abstractThe heat capacity of deuterated ammonium hexachloroplatinate (ND4)2PtCl6 was measured at temperatures from 5 K to 350 K by adiabatic calorimetry. One &#x03bb;-shaped anomaly, absent in the undeuterated salt, was found in the curve for heat capacity against temperature. This &#x03bb;-shaped transition reaches its maximum Cp,m [approximate] 59.3&#x00b7;R at (27.2&#x00b1;0.05) K with &#x0394;trsSom = (1.216&#x00b1;0.004)&#x00b7;R, characteristic of an order-disorder transition. Smoothed values of the standard thermodynamic quantities for pure (ND4)2PtCl6 are tabulated at temperatures up to 350 K.en_US
dc.format.extent672647 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleThermodynamic properties of ammonium haloplatinates: II. Heat capacity and thermodynamic functions of deuterated ammonium hexachloroplatinate (ND4)2PtCl6 at temperatures from 5 K to 350 Ken_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry and Chemical Engineering, Royal Military College of Canada, Kingston, Ontario K7K 5L0, Canada;Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry and Chemical Engineering, Royal Military College of Canada, Kingston, Ontario K7K 5L0, Canada;Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/29263/1/0000321.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0021-9614(05)80203-4en_US
dc.identifier.sourceThe Journal of Chemical Thermodynamicsen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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