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An intramolecular, Schmidt reaction of an alkyl azide with a carbocation. The generation and rearrangement of a conformationally restricted secondary aminodiazonium ion.

dc.contributor.authorPearson, William H.en_US
dc.contributor.authorSchkeryantz, Jeffrey M.en_US
dc.date.accessioned2006-04-10T15:05:12Z
dc.date.available2006-04-10T15:05:12Z
dc.date.issued1992-09-08en_US
dc.identifier.citationPearson,, William H., Schkeryantz, Jeffrey M. (1992/09/08)."An intramolecular, Schmidt reaction of an alkyl azide with a carbocation. The generation and rearrangement of a conformationally restricted secondary aminodiazonium ion.." Tetrahedron Letters 33(37): 5291-5294. <http://hdl.handle.net/2027.42/29850>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THS-42HX73T-PP/2/e40fb8c0824db52c378c95f04eb950d6en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/29850
dc.description.abstractTreatment of azidoalkene 2 with triflic acid produced the bridged bicyclic enamine 3 by an intramolecular Schmidt reaction. Rearrangement of the intermediate aminodiazonium ion 5 is completely regioselective.en_US
dc.format.extent282849 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleAn intramolecular, Schmidt reaction of an alkyl azide with a carbocation. The generation and rearrangement of a conformationally restricted secondary aminodiazonium ion.en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109-1055 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109-1055 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/29850/1/0000197.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0040-4039(00)79075-7en_US
dc.identifier.sourceTetrahedron Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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