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Normal-mode analysis of infrared and Raman spectra of poly(vinyl fluoride)
dc.contributor.authorHong, J. W.en_US
dc.contributor.authorLando, J. B.en_US
dc.contributor.authorKoenig, J. L.en_US
dc.contributor.authorChough, Sung Hyoen_US
dc.contributor.authorKrimm, Samuelen_US
dc.date.accessioned2006-04-10T15:17:50Z
dc.date.available2006-04-10T15:17:50Z
dc.date.issued1992-03-02en_US
dc.identifier.citationHong, J. W., Lando, J. B., Koenig, J. L., Chough, S. H., Krimm, S. (1992/03/02)."Normal-mode analysis of infrared and Raman spectra of poly(vinyl fluoride)." Vibrational Spectroscopy 3(1): 55-66. <http://hdl.handle.net/2027.42/30156>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THW-44XN19C-1S/2/39c2aeb3c3a2b27b305ce253a2de0ec2en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/30156
dc.description.abstractInfrared and Raman spectra of samples of poly(vinyl fluoride) (PVF) have been recorded. The vibrational spectra have been analyzed by means of normal-mode calculations. A force field was derived by using 2-fluorobutane as a model compound. Crowder's force field for hydrofluorocarbons was employed as a starting point and subsequently refined in application to secondary fluorides. A planar zigzag, syndiotactic single-chain model of crystalline PVF was submitted to be analyzed by this scheme. A comparison of observed infrared and Raman bands with frequencies calculated for syndiotactic PVF shows that PVF produced by conventional free radical polymerization has an atactic structure, supporting the 19F-NMR results and conclusions reached by Koenig and Boerio. Band assignments in terms of atactic structure are proposed.en_US
dc.format.extent1001269 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleNormal-mode analysis of infrared and Raman spectra of poly(vinyl fluoride)en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Physics & Macromolecular Research Center, University of Michigan, Ann Arbor, MI 48109 USAen_US
dc.contributor.affiliationumDepartment of Physics & Macromolecular Research Center, University of Michigan, Ann Arbor, MI 48109 USAen_US
dc.contributor.affiliationotherDepartment of Macromolecular Science, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7202 USAen_US
dc.contributor.affiliationotherDepartment of Macromolecular Science, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7202 USAen_US
dc.contributor.affiliationotherDepartment of Macromolecular Science, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7202 USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/30156/1/0000533.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0924-2031(92)85024-Uen_US
dc.identifier.sourceVibrational Spectroscopyen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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