Shape-selective separation of polycyclic aromatic hydrocarbons by reversed-phase liquid chromatography on tetraphenylporphyrin-based stationary phases
dc.contributor.author | Kibbey, Christopher E. | en_US |
dc.contributor.author | Meyerhoff, Mark E. | en_US |
dc.date.accessioned | 2006-04-10T15:40:34Z | |
dc.date.available | 2006-04-10T15:40:34Z | |
dc.date.issued | 1993-07-02 | en_US |
dc.identifier.citation | Kibbey, Chris E., Meyerhoff, Mark E. (1993/07/02)."Shape-selective separation of polycyclic aromatic hydrocarbons by reversed-phase liquid chromatography on tetraphenylporphyrin-based stationary phases." Journal of Chromatography A 641(1): 49-55. <http://hdl.handle.net/2027.42/30686> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TG8-44CPX4R-WM/2/b3087c5bf37b04910b1e5a9e89d9ef42 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/30686 | |
dc.identifier.uri | http://www.ncbi.nlm.nih.gov/sites/entrez?cmd=retrieve&db=pubmed&list_uids=8349741&dopt=citation | en_US |
dc.description.abstract | The reversed-phase chromatographic behavior of planar and non-planar polycyclic aromatic hydrocarbons (PAHs) is investigated on tetraphenylporphyrin and two metallotetraphenylporphyrin [Sn(IV), In(III)] bonded stationary phases using methanol--water and acetonitrile--water as mixed solvent mobile phases. Large differences in the capacity factors of aromatic solute pairs having the same number of carbon atoms, but differing in three-dimensional shape (e.g., triphenylene/o-terphenyl and perylene/[alpha], [alpha]'-binaphthyl), suggest that the three tetraphenylporphyrin-based supports possess shape selectivity toward small planar aromatic solutes. Capacity factors for planar PAH solutes on these supports are significantly greater than for non-planar polyaryls having the same number of carbon atoms. | en_US |
dc.format.extent | 700862 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Shape-selective separation of polycyclic aromatic hydrocarbons by reversed-phase liquid chromatography on tetraphenylporphyrin-based stationary phases | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Public Health | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109 USA | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109 USA | en_US |
dc.identifier.pmid | 8349741 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/30686/1/0000331.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9673(93)83457-4 | en_US |
dc.identifier.source | Journal of Chromatography A | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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