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Manganese carbonyl complexes of 2,5-dimethylbismolyl. The crystal and molecular structure of ([eta]1-2,5-dimethylbismolyl) manganese pentacarbonyl

dc.contributor.authorAshe, Arthur J. IIIen_US
dc.contributor.authorKampf, Jeffrey W.en_US
dc.contributor.authorPuranik, Dhananjay B.en_US
dc.date.accessioned2006-04-10T15:47:47Z
dc.date.available2006-04-10T15:47:47Z
dc.date.issued1993-04-06en_US
dc.identifier.citationAshe, III, Arthur J., Kampf, Jeff W., Puranik, Dhananjay B. (1993/04/06)."Manganese carbonyl complexes of 2,5-dimethylbismolyl. The crystal and molecular structure of ([eta]1-2,5-dimethylbismolyl) manganese pentacarbonyl." Journal of Organometallic Chemistry 447(2): 197-201. <http://hdl.handle.net/2027.42/30847>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGW-436F9HS-5W/2/196478102f70352bc99645857639cbdben_US
dc.identifier.urihttps://hdl.handle.net/2027.42/30847
dc.description.abstract([eta]-1-2,5-Dimethylbismolyl)manganese pentacarbonyl (8) has been obtained from the reaction of 1-phenyl-2,5-dimethylbismole with lithium followed by BrMn(CO)5. Heating 8 to its melting point causes the loss of CO to produce ([eta]5-2,5-dimethylbismolyl)manganese tricarbonyl. Compound 8 crystallizes in the monoclinic crystal system, space group P 21 (No. 4) with a = 6.838(2) A, b = 6.424(1) A, c = 15.787(4) A, [beta] = 95.68(2)[deg] V= 6901.(2) A3 and Z = 2. A full structure has been determined and is compared with those of analogous compounds.en_US
dc.format.extent316360 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleManganese carbonyl complexes of 2,5-dimethylbismolyl. The crystal and molecular structure of ([eta]1-2,5-dimethylbismolyl) manganese pentacarbonylen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109-1055 USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109-1055 USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109-1055 USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/30847/1/0000509.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-328X(93)80238-7en_US
dc.identifier.sourceJournal of Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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