Application of the 2-azaallyl anion cycloaddition method to syntheses of (+/-)-crinine and (+/-)-6-epicrinine
dc.contributor.author | Pearson, William H. | en_US |
dc.contributor.author | Lovering, Frank E. | en_US |
dc.date.accessioned | 2006-04-10T17:42:32Z | |
dc.date.available | 2006-04-10T17:42:32Z | |
dc.date.issued | 1994-12-05 | en_US |
dc.identifier.citation | Pearson,, William H., Lovering, Frank E. (1994/12/05)."Application of the 2-azaallyl anion cycloaddition method to syntheses of (+/-)-crinine and (+/-)-6-epicrinine." Tetrahedron Letters 35(49): 9173-9176. <http://hdl.handle.net/2027.42/31137> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6THS-42NJDJ5-1W/2/43f78865e6a784835cc87342648b763c | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/31137 | |
dc.description.abstract | Transmetalation of the (2-azaallyl)stannane 9 with n-BuLi produced the 2-azaallyl anion 12 which underwent an intramolecular cycloaddition with an alkene to give the perhydroindole 10 in 80% yield as a single stereoisomer. Transformation of 10 to 6-epicrinine 2 and crinine 1 was readily accomplished. | en_US |
dc.format.extent | 228663 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Application of the 2-azaallyl anion cycloaddition method to syntheses of (+/-)-crinine and (+/-)-6-epicrinine | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, MI 48109-1055 USA | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, MI 48109-1055 USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/31137/1/0000034.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0040-4039(94)88457-9 | en_US |
dc.identifier.source | Tetrahedron Letters | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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