Thermodynamics of the thallium alkanoates VIII. Heat capacity and derived thermophysical properties of thallium(I) propanoate and pentanoate at temperatures from 6 K to 490 K
dc.contributor.author | Fernandez-Martin, F. | en_US |
dc.contributor.author | Cheda, Jose A. R. | en_US |
dc.contributor.author | Jones, L. L. | en_US |
dc.contributor.author | Lin, C. C. | en_US |
dc.contributor.author | Westrum, Jr. , Edgar F. | en_US |
dc.date.accessioned | 2006-04-10T17:56:45Z | |
dc.date.available | 2006-04-10T17:56:45Z | |
dc.date.issued | 1994-09 | en_US |
dc.identifier.citation | Fernandez-Martin, F., Cheda, J. A. R., Jones, L. L., Lin, C. C., Westrum, Jr., Edgar F. (1994/09)."Thermodynamics of the thallium alkanoates VIII. Heat capacity and derived thermophysical properties of thallium(I) propanoate and pentanoate at temperatures from 6 K to 490 K." The Journal of Chemical Thermodynamics 26(9): 925-940. <http://hdl.handle.net/2027.42/31375> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-45P0SF1-W/2/0add29450699b9c5f1785ca3027ad107 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/31375 | |
dc.description.abstract | Heat-capacity measurements by adiabatic calorimetry at temperature T = 5 K to 350 K were supplemented by differential-scanning calorimetry (d.s.c.) into the liquid region on thallium(I) propanoate and pentanoate. Apparent phase transitions were noted for the propanoate for the crystal III-to-crystal II transition with [Delta]transSom = (1.473+/-0.001)R at T = (277.7+/-0.1) K adiabatic calorimetry and for the crystal II-to-crystal I transition at (0.10+/-0.01)R at T = (268.4+/-0.4) K by d.s.c. and for the crystal I-to-liquid transition with [Delta]trsSom = (2.70+/-0.09) R at T = (468.0+/-0.4) K. For the VI-to-V and V-to-IV transitions of the pentanoate by adiabatic calorimetry the corresponding values are (0.359+/-0.002)R and (235.1+/-0.1) K, (1.511+/-0.003)R and (219.3+/-1) K. For the IV-to-III, III-to-II, II-to-I, plus crystal I-to-mesophase and mesophase-to-isotropic liquid for the same compound the pairs of values by d.s.c. (only) are: (0.26+/-0.02)R and (234.6+/-0.4) K; (1.00+/-0.04)R and (284.5+/-0.4) K; (0.72+/-0.03)R and (353.0+/-0.4) K; (1.50+/-0.05)R and (455.0+/-0.5) K; and (0.75+/-0.04)R and (488.0 +/-0.8) K. Like thallium(I) butanoate, the propanoate does not show a mesotropic liquid phase. | en_US |
dc.format.extent | 442998 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Thermodynamics of the thallium alkanoates VIII. Heat capacity and derived thermophysical properties of thallium(I) propanoate and pentanoate at temperatures from 6 K to 490 K | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Instituto del Frio, CSIC, Ciudad Universitaria, 28040 Madrid, Spain; Departamento de Química Física, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain and Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, U.S.A. | en_US |
dc.contributor.affiliationum | Instituto del Frio, CSIC, Ciudad Universitaria, 28040 Madrid, Spain; Departamento de Química Física, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain and Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, U.S.A. | en_US |
dc.contributor.affiliationum | Instituto del Frio, CSIC, Ciudad Universitaria, 28040 Madrid, Spain; Departamento de Química Física, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain and Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, U.S.A. | en_US |
dc.contributor.affiliationum | Instituto del Frio, CSIC, Ciudad Universitaria, 28040 Madrid, Spain; Departamento de Química Física, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain and Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, U.S.A. | en_US |
dc.contributor.affiliationum | Instituto del Frio, CSIC, Ciudad Universitaria, 28040 Madrid, Spain; Departamento de Química Física, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain and Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/31375/1/0000288.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1006/jcht.1994.1110 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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