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An evaluation of the rotational barrier about the B---N bond of 1-aminoborepins

dc.contributor.authorAshe, Arthur J. IIIen_US
dc.contributor.authorKlein, Wolframen_US
dc.contributor.authorRousseau, Rogeren_US
dc.date.accessioned2006-04-10T18:13:21Z
dc.date.available2006-04-10T18:13:21Z
dc.date.issued1994-04-05en_US
dc.identifier.citationAsheIII, Arthur J., Klein, Wolfram, Rousseau, Roger (1994/04/05)."An evaluation of the rotational barrier about the B---N bond of 1-aminoborepins." Journal of Organometallic Chemistry 468(1-2): 21-23. <http://hdl.handle.net/2027.42/31643>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGW-42T5P2Y-1W/2/d3fa68ff5843771ff1f322012a07c413en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/31643
dc.description.abstract13C NMR spectroscopy has been used to determined the barriers to rotation about the B---N bonds of 1-(N-benzyl-N-methylamino)borepin and 1-(N-benzyl-N-methylamino)-4,5-dihydroborepin as 18 and 19.8 kcal mol-1, respectively. The corresponding rotational barriers of a variety of aminoboranes have been calculated using the semi-empirical AM1 method.en_US
dc.format.extent330068 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleAn evaluation of the rotational barrier about the B---N bond of 1-aminoborepinsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/31643/1/0000577.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-328X(94)80025-1en_US
dc.identifier.sourceJournal of Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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