An evaluation of the rotational barrier about the B---N bond of 1-aminoborepins
dc.contributor.author | Ashe, Arthur J. III | en_US |
dc.contributor.author | Klein, Wolfram | en_US |
dc.contributor.author | Rousseau, Roger | en_US |
dc.date.accessioned | 2006-04-10T18:13:21Z | |
dc.date.available | 2006-04-10T18:13:21Z | |
dc.date.issued | 1994-04-05 | en_US |
dc.identifier.citation | AsheIII, Arthur J., Klein, Wolfram, Rousseau, Roger (1994/04/05)."An evaluation of the rotational barrier about the B---N bond of 1-aminoborepins." Journal of Organometallic Chemistry 468(1-2): 21-23. <http://hdl.handle.net/2027.42/31643> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TGW-42T5P2Y-1W/2/d3fa68ff5843771ff1f322012a07c413 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/31643 | |
dc.description.abstract | 13C NMR spectroscopy has been used to determined the barriers to rotation about the B---N bonds of 1-(N-benzyl-N-methylamino)borepin and 1-(N-benzyl-N-methylamino)-4,5-dihydroborepin as 18 and 19.8 kcal mol-1, respectively. The corresponding rotational barriers of a variety of aminoboranes have been calculated using the semi-empirical AM1 method. | en_US |
dc.format.extent | 330068 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | An evaluation of the rotational barrier about the B---N bond of 1-aminoborepins | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, USA | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, USA | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/31643/1/0000577.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0022-328X(94)80025-1 | en_US |
dc.identifier.source | Journal of Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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