Characteristic infrared frequencies of rotational isomers of alkyl chlorides
dc.contributor.author | Shipman, J. J. | en_US |
dc.contributor.author | Folt, V. L. | en_US |
dc.contributor.author | Krimm, Samuel | en_US |
dc.date.accessioned | 2006-04-13T14:56:37Z | |
dc.date.available | 2006-04-13T14:56:37Z | |
dc.date.issued | 1962 | en_US |
dc.identifier.citation | Shipman, J.J., Folt, V.L., Krimm, S. (1962)."Characteristic infrared frequencies of rotational isomers of alkyl chlorides." Spectrochimica Acta 18(4): 1603-1613. <http://hdl.handle.net/2027.42/32341> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6W98-4FW6JX5-3J/2/297296078be9c556126a8cb9793203dd | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/32341 | |
dc.description.abstract | A study of the infrared spectra of primary, secondary and tertiary alkyl chlorides reveals that the frequency of the so-called C-Cl stretching mode is a function of the detailed structure in the vicinity of the C-Cl bond. In primary chlorides the frequency region depends on whether a hydrogen atom or a carbon atom is irons to the Cl atom across the common C-C bond. In secondary chlorides it is found that the trans substituents on both C-C bonds adjacent to the C-Cl bond are important in determining the frequency region, and a similar result is observed for the tertiary chlorides. Frequency ranges for the various rotationally isomeric structures of primary, secondary and tertiary chlorides are given. | en_US |
dc.format.extent | 2378841 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Characteristic infrared frequencies of rotational isomers of alkyl chlorides | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan, USA | en_US |
dc.contributor.affiliationother | The B. F. Goodrich Company, Research Center, Brecksville, Ohio, USA | en_US |
dc.contributor.affiliationother | The B. F. Goodrich Company, Research Center, Brecksville, Ohio, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/32341/1/0000411.pdf | en_US |
dc.identifier.source | Spectrochimica Acta | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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