Pyrimidine in aqueous media
dc.contributor.author | O'Reilly, James S. | en_US |
dc.contributor.author | Elving, Philip Juliber | en_US |
dc.date.accessioned | 2006-04-17T15:21:01Z | |
dc.date.available | 2006-04-17T15:21:01Z | |
dc.date.issued | 1969-04 | en_US |
dc.identifier.citation | O'Reilly, James S., Elving, Philip J. (1969/04)."Pyrimidine in aqueous media." Journal of Electroanalytical Chemistry 21(1): 169-179. <http://hdl.handle.net/2027.42/32988> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TGB-44YPVJR-H/2/3f9b0a6167ee022f31115342a9023413 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/32988 | |
dc.description.abstract | The electrochemical reduction of pyrimidine in aqueous media was studied using alternating current (a.c.) polarography. Over the pH-range, 0.5-13, five moderately to highly irreversible a.c. waves were observed, which corresponded to the five waves observed on d.c. polarography. Although the electrochemical reduction path of pyrimidine is complex and only partially understood, good qualitative agreement between the features of the mechanism and various polarographic parameters was achieved, providing further support for the proposed mechanism, and indicaing the validity of the current theoretical and experimental results in the area of the a.c. polarography of quasi-reversible electrode reactions. Summit potentials for the five waves, which vary linearly with pH, are independent of applied alternating voltage, mercury column height (drop-time) and concentration, but shift to more negative potential with increasing frequency. Total alternating current for all waves increases linearly with amplitude of applied alternating voltage and the negative square root of droptime; plots of total alternating current vs. square root of applied frequency exhibit curvilinear trends with a maximum in the range, 15-50 Hz. | en_US |
dc.format.extent | 577636 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Pyrimidine in aqueous media | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | University of Michigan, Ann Arbor, Mich. U.S.A. | en_US |
dc.contributor.affiliationum | University of Michigan, Ann Arbor, Mich. U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/32988/1/0000372.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0368-1874(69)89015-5 | en_US |
dc.identifier.source | Journal of Electroanalytical Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.