Solubilization of water by dialkyl sodium sulfosuccinates in hydrocarbon solutions
dc.contributor.author | Frank, Sylvan G. | en_US |
dc.contributor.author | Zografi, George | en_US |
dc.date.accessioned | 2006-04-17T15:23:25Z | |
dc.date.available | 2006-04-17T15:23:25Z | |
dc.date.issued | 1969-01 | en_US |
dc.identifier.citation | Frank, Sylvan G., Zografi, George (1969/01)."Solubilization of water by dialkyl sodium sulfosuccinates in hydrocarbon solutions." Journal of Colloid and Interface Science 29(1): 27-35. <http://hdl.handle.net/2027.42/33042> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHR-4CTN0R2-SK/2/806fd561d0f77ed9a9729af71e178380 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/33042 | |
dc.identifier.uri | http://www.ncbi.nlm.nih.gov/sites/entrez?cmd=retrieve&db=pubmed&list_uids=5764728&dopt=citation | en_US |
dc.description.abstract | The apparent solubilization of water in hydrocarbon solvents by the addition of 0.1% to 2.0% w/w di-(2-ethylhexyl) sodium sulfosuccinate (AOT) has been studied. In n-octane and n-decane, transitions of clear-turbid-clear-turbid were observed with increasing water content, whereas in dodecane, tetradecane, hexadecane, cyclohexane, and toluene only one clear-turbid transition was seen. Separation of the first turbid region in n-octane and n-decane gave two clear phases. Direct analysis indicates a hydrocarbon phase containing surfactant-solubilized water and an aqueous phase containing some surfactant. Increasing amounts of water partition between these phases until a second clear region appears. Separation of phases in the second turbid region in n-octane and n-decane and in the turbid region of the other solvents produces a pure hydrocarbon phase and a phase containing a complex aggregate of AOT/water/hydrocarbon. Solubilization of water in n-octane solutions of di-(n-octyl) sodium sulfosuccinate and di-(n-hexyl) sodium sulfosuccinate is greatly reduced when compared to AOT. This suggests a significant effect due to the ethyl side chain in the AOT molecule. | en_US |
dc.format.extent | 749860 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Solubilization of water by dialkyl sodium sulfosuccinates in hydrocarbon solutions | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | College of Pharmacy, University of Michigan, Ann Arbor, Michigan 48103, USA | en_US |
dc.contributor.affiliationum | College of Pharmacy, University of Michigan, Ann Arbor, Michigan 48103, USA | en_US |
dc.identifier.pmid | 5764728 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/33042/1/0000428.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9797(69)90342-7 | en_US |
dc.identifier.source | Journal of Colloid and Interface Science | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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