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Structure and vibrational assignments for PCl5 : An electron diffraction study
dc.contributor.authorAdams, W. J.en_US
dc.contributor.authorBartell, Lawrence S.en_US
dc.date.accessioned2006-04-17T16:27:49Z
dc.date.available2006-04-17T16:27:49Z
dc.date.issued1971-04en_US
dc.identifier.citationAdams, W. J., Bartell, L. S. (1971/04)."Structure and vibrational assignments for PCl5 : An electron diffraction study." Journal of Molecular Structure 8(1-2): 23-30. <http://hdl.handle.net/2027.42/33673>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGS-44KR446-G9/2/1654c98a3d634d4b86210ef2bcc7e44ben_US
dc.identifier.urihttps://hdl.handle.net/2027.42/33673
dc.description.abstractGas-phase phosphorus pentachloride is a trigonal bipyramid with axial bonds 0.104+/-0.01 A (e.s.d.) longer than equatorial bonds. The mean bond lengths are 2.061+/-0.002 A. Amplitudes of vibration were determined, resolving the ambiguity in the e1' bending assignments in favor of v(axial bend) &gt; v(equatorial in-plane bend). Structural and vibrational features were in accord with Gillespie-Nyholm theory.en_US
dc.format.extent693119 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleStructure and vibrational assignments for PCl5 : An electron diffraction studyen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumUniversity of Michigan, Ann Arbor, Mich. 48104 U.S.A.en_US
dc.contributor.affiliationumUniversity of Michigan, Ann Arbor, Mich. 48104 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/33673/1/0000185.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-2860(71)80038-8en_US
dc.identifier.sourceJournal of Molecular Structureen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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