The magnetic transition, heat capacity, and thermodynamic properties of uranium dioxide from 5 to 350 K
dc.contributor.author | Huntzicker, James J. | en_US |
dc.contributor.author | Westrum, Jr. , Edgar F. | en_US |
dc.date.accessioned | 2006-04-17T16:30:29Z | |
dc.date.available | 2006-04-17T16:30:29Z | |
dc.date.issued | 1971-01 | en_US |
dc.identifier.citation | Huntzicker, James J., Westrum, Jr., Edgar F. (1971/01)."The magnetic transition, heat capacity, and thermodynamic properties of uranium dioxide from 5 to 350 K." The Journal of Chemical Thermodynamics 3(1): 61-76. <http://hdl.handle.net/2027.42/33729> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-4H2FSTM-8/2/6ecbbd98bf8a058902a740ad28fec878 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/33729 | |
dc.description.abstract | The heat capacity of high purity uranium dioxide has been re-examined over the low-temperature range especially in the vicinity of the λ-type anomaly reported to occur at 28·7 K as a consequence of magnetic ordering. The present study indicates a very sharp transition at 30·44 K with a maximum Cp of 391 cal mol-1 K-1. The heat capacity at constant pressure Cp, the entropy S°, the enthalpy (H° - H°0), and Gibbs energy function (G° - H°)/T are tabulated and at 298.15 K have the following values: 15.20 cal mol-1 K-1, 18.41 cal mol-1 K-1, 2696 cal mol-1 K-1, and -9.37 cal mol-1 K-1. The heat capacity results are compared with those derived from the neutron scattering work and also with the theory of Allen. | en_US |
dc.format.extent | 995267 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | The magnetic transition, heat capacity, and thermodynamic properties of uranium dioxide from 5 to 350 K | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/33729/1/0000242.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/S0021-9614(71)80067-8 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.