Synthesis and homopolymerization studies of vinylimidazolium salts
dc.contributor.author | Salamone, J. C. (Joseph C.) | en_US |
dc.contributor.author | Israel, S. C. | en_US |
dc.contributor.author | Taylor, P. | en_US |
dc.contributor.author | Snider, B. | en_US |
dc.date.accessioned | 2006-04-17T16:33:31Z | |
dc.date.available | 2006-04-17T16:33:31Z | |
dc.date.issued | 1973-12 | en_US |
dc.identifier.citation | Salamone, J. C., Israel, S. C., Taylor, P., Snider, B. (1973/12)."Synthesis and homopolymerization studies of vinylimidazolium salts." Polymer 14(12): 639-644. <http://hdl.handle.net/2027.42/33769> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TXW-48FBXSF-139/2/cd2970baeaa248e5995d23ad06c2f74c | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/33769 | |
dc.description.abstract | The preparations and characterizations of several monomeric vinylimidazolium salts are presented from the quaternizations of 1-vinylimidazole and 2-methyl-1-vinylimidazole with n-alkyl iodides and with dimethyl sulphate. Although vinylimidazolium salts have been reported in the patent literature, many of these salts were not isolated and characterized prior to their polymerization. From the reactions of 1-vinylimidazole with n-alkyl iodides, a homologous series of 3-n-alkyl-1-vinylimidazolium iodides were prepared in which the longer chain derivatives appeared to form micelles in aqueous solution. Dicationic crosslinking agents were also prepared through similar quaternization reactions. All the cationic vinyl monomers were homopolymerized in aqueous solution by free radical initiation. The solution behaviour of the resulting polyions indicated that the longer side-chain polyions had polysoap properties. | en_US |
dc.format.extent | 712244 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Synthesis and homopolymerization studies of vinylimidazolium salts | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Management | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Economics | en_US |
dc.subject.hlbtoplevel | Business | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Polymer Science Program, Department of Chemistry, Lowell Technological Institute, Lowell, Mass. 01854, USA; Macromolecular Research Center, University of Michigan, Ann Arbor, Michigan 41805, USA. | en_US |
dc.contributor.affiliationum | Macromolecular Research Center, University of Michigan, Ann Arbor, Michigan 41805, USA; Polymer Science Program, Department of Chemistry, Lowell Technological Institute, Lowell, Mass. 01854, USA. | en_US |
dc.contributor.affiliationum | Macromolecular Research Center, University of Michigan, Ann Arbor, Michigan 41805, USA; Polymer Science Program, Department of Chemistry, Lowell Technological Institute, Lowell, Mass. 01854, USA. | en_US |
dc.contributor.affiliationum | Macromolecular Research Center, University of Michigan, Ann Arbor, Michigan 41805, USA; Polymer Science Program, Department of Chemistry, Lowell Technological Institute, Lowell, Mass. 01854, USA. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/33769/1/0000021.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0032-3861(73)90039-6 | en_US |
dc.identifier.source | Polymer | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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