Selective transfers of acetylenic acids to form lecithins
dc.contributor.author | Tama1, Yoichi | en_US |
dc.contributor.author | Lands, William E. M. | en_US |
dc.contributor.author | Barve, John A. | en_US |
dc.contributor.author | Gunstone, Frank D. | en_US |
dc.date.accessioned | 2006-04-17T16:40:59Z | |
dc.date.available | 2006-04-17T16:40:59Z | |
dc.date.issued | 1973-03-08 | en_US |
dc.identifier.citation | Tama1, Yoichi, Lands, William E. M., Barve, J. A., Gunstone, Frank D. (1973/03/08)."Selective transfers of acetylenic acids to form lecithins." Biochimica et Biophysica Acta (BBA) - Lipids and Lipid Metabolism 296(3): 563-571. <http://hdl.handle.net/2027.42/33918> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6T1X-47G2RKF-6C/2/02c14861666b48cb48e0f91490c8d7c0 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/33918 | |
dc.identifier.uri | http://www.ncbi.nlm.nih.gov/sites/entrez?cmd=retrieve&db=pubmed&list_uids=4688639&dopt=citation | en_US |
dc.description.abstract | Although acetylenic acids are not normally found in mammalian tissues, octadecynoyl-CoA esters can serve as substrates for rat liver microsomal acyl-CoA: phospholipid acyltransferases. The relatively high rate of transfer to the 2-hydroxyl of 1-acylglycerol-3-phosphorylcholine by the 5-, 9-, and 12-positional cis, trans and yne isomers of acids supports the concept that [pi]-bonds at these positions facilitate esterification irrespective of configuration. The preferred positional isomers for transfer to the 1-hydroxyl, however, are different for the cis and yne derivatives, indicating a sensitivity of the enzyme(s) to configuration. In the latter transfer, an alternating selectivity occurred with the acetylenic isomers between 8 to 13 that was opposite to the pattern for the cis-octadecenoyl transfers. | en_US |
dc.format.extent | 569313 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Selective transfers of acetylenic acids to form lecithins | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Biological Chemistry, University of Michigan, Ann Arbor, Mich. 48104, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Biological Chemistry, University of Michigan, Ann Arbor, Mich. 48104, U.S.A. | en_US |
dc.contributor.affiliationother | Department of Chemistry, St. Andrews University, St. Andrews, Great Britain | en_US |
dc.contributor.affiliationother | Department of Chemistry, St. Andrews University, St. Andrews, Great Britain | en_US |
dc.identifier.pmid | 4688639 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/33918/1/0000184.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0005-2760(73)90116-1 | en_US |
dc.identifier.source | Biochimica et Biophysica Acta | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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