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Trimethylstannyl-2,4-cycloheptadiene: A fluxional molecule

dc.contributor.authorDavid Curtis, M.en_US
dc.contributor.authorFink, Roberten_US
dc.date.accessioned2006-04-17T16:49:36Z
dc.date.available2006-04-17T16:49:36Z
dc.date.issued1972-05-16en_US
dc.identifier.citationDavid Curtis, M., Fink, Robert (1972/05/16)."Trimethylstannyl-2,4-cycloheptadiene: A fluxional molecule." Journal of Organometallic Chemistry 38(2): 299-305. <http://hdl.handle.net/2027.42/34105>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGW-42TC5YK-PH/2/fb0c8a142d9b9cd091d3a43b790cb200en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/34105
dc.description.abstractTrimethylstannyl-2,4-cycloheptadiene (II) was synthesized and shown to be fluxional on the NMR time scale. The activation energy for the [1,5] trimethyltin migration is estimated to be ca. 18 kcal/mole. This value is compared with estimated activation energies of 14 kcal/mole for trimethylstannylindene (IV) and 6 kcal/mole for cyclopentadienyltrimethylstannane (I, E=Sn). 1,1-Dimethyl-4-trimethylstannyl-2,5-cyclohexadiene (VIII) was also synthesized and was shown to be non-fluxional.en_US
dc.format.extent437203 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleTrimethylstannyl-2,4-cycloheptadiene: A fluxional moleculeen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/34105/1/0000387.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0022-328X(00)83332-Xen_US
dc.identifier.sourceJournal of Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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