Trimethylstannyl-2,4-cycloheptadiene: A fluxional molecule
dc.contributor.author | David Curtis, M. | en_US |
dc.contributor.author | Fink, Robert | en_US |
dc.date.accessioned | 2006-04-17T16:49:36Z | |
dc.date.available | 2006-04-17T16:49:36Z | |
dc.date.issued | 1972-05-16 | en_US |
dc.identifier.citation | David Curtis, M., Fink, Robert (1972/05/16)."Trimethylstannyl-2,4-cycloheptadiene: A fluxional molecule." Journal of Organometallic Chemistry 38(2): 299-305. <http://hdl.handle.net/2027.42/34105> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TGW-42TC5YK-PH/2/fb0c8a142d9b9cd091d3a43b790cb200 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/34105 | |
dc.description.abstract | Trimethylstannyl-2,4-cycloheptadiene (II) was synthesized and shown to be fluxional on the NMR time scale. The activation energy for the [1,5] trimethyltin migration is estimated to be ca. 18 kcal/mole. This value is compared with estimated activation energies of 14 kcal/mole for trimethylstannylindene (IV) and 6 kcal/mole for cyclopentadienyltrimethylstannane (I, E=Sn). 1,1-Dimethyl-4-trimethylstannyl-2,5-cyclohexadiene (VIII) was also synthesized and was shown to be non-fluxional. | en_US |
dc.format.extent | 437203 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Trimethylstannyl-2,4-cycloheptadiene: A fluxional molecule | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104 U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104 U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/34105/1/0000387.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/S0022-328X(00)83332-X | en_US |
dc.identifier.source | Journal of Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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