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The reaction of H 8 Si 8 O 12 with a chromium oxide surface: a model for stainless steel surface modification
dc.contributor.authorGreeley, J. N.en_US
dc.contributor.authorLee, S.en_US
dc.contributor.authorBanaszak Holl, Mark M.en_US
dc.date.accessioned2006-04-19T13:48:09Z
dc.date.available2006-04-19T13:48:09Z
dc.date.issued1999-04en_US
dc.identifier.citationGreeley, J. N.; Lee, S.; Banaszak Holl, M. M. (1999)."The reaction of H 8 Si 8 O 12 with a chromium oxide surface: a model for stainless steel surface modification." Applied Organometallic Chemistry 13(4): 279-285. <http://hdl.handle.net/2027.42/34739>en_US
dc.identifier.issn0268-2605en_US
dc.identifier.issn1099-0739en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/34739
dc.description.abstractMany metal alloys are susceptible to corrosion, particularly after processing steps such as welding. Chemical vapor deposition (CVD) is an effective way to modify metal surfaces and impart specific physical and chemical properties. A hydrophobic, nanosegmented silicon oxide coating derived from the discrete cluster molecule H 8 Si 8 O 12 has been shown to chemisorb to 302 and 304 stainless steel. To understand better how this cluster binds to steel, a comprehensive study of these clusters adsorbed on chromium oxide was undertaken. IR, XPS and valence-band spectroscopies show convincingly that the clusters are chemisorbed intact on this surface. The coating also readily forms on molybdenum, tungsten, iron and nickel oxides, promising general application to a wide variety of metal alloys. Copyright © 1999 John Wiley & Sons, Ltd.en_US
dc.format.extent86436 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherJohn Wiley & Sons, Ltd.en_US
dc.subject.otherChemistryen_US
dc.subject.otherIndustrial Chemistry and Chemical Engineeringen_US
dc.titleThe reaction of H 8 Si 8 O 12 with a chromium oxide surface: a model for stainless steel surface modificationen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumChemistry Department, University of Michigan, Ann Arbor, MI 48109-1055, USAen_US
dc.contributor.affiliationumChemistry Department, University of Michigan, Ann Arbor, MI 48109-1055, USA ; Chemistry Department, University of Michigan, Ann Arbor, MI 48109-1055, USAen_US
dc.contributor.affiliationotherChemistry Department, Brown University, Providence, RI 02912, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/34739/1/843_ftp.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1002/(SICI)1099-0739(199904)13:4<279::AID-AOC843>3.0.CO;2-Nen_US
dc.identifier.sourceApplied Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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