A study of consecutive competitive reaction systems
dc.contributor.author | Friedman, Morton H. | en_US |
dc.contributor.author | White, Robert R. | en_US |
dc.date.accessioned | 2006-04-28T15:41:39Z | |
dc.date.available | 2006-04-28T15:41:39Z | |
dc.date.issued | 1962-11 | en_US |
dc.identifier.citation | Friedman, M. H.; White, R. R. (1962)."A study of consecutive competitive reaction systems." AIChE Journal 8(5): 581-586. <http://hdl.handle.net/2027.42/37325> | en_US |
dc.identifier.issn | 0001-1541 | en_US |
dc.identifier.issn | 1547-5905 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/37325 | |
dc.description.abstract | Experimental kinetic data are most conveniently correlated by the integrated form of the differential rate equations which the reactions are presumed to obey. A new method of obtaining an approximate integral solution of the differential equations is described and applied to a set of three consecutive competitive reactions. The approximate integral solution is used to correlate experimental data on systems whose stoichiometry would indicate a consecutivecompetitive mechanism. The compositions of the reaction mixes are predicted with a standard error of estimate of less than 4% of the original concentration of the initiating reactant, in most cases less than 2%. The estimates of the rate constants, found by fitting the approximate solution to the data, are within experimental error of the values obtained by differentiation of the published results. | en_US |
dc.format.extent | 700494 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | American Institute of Chemical Engineers | en_US |
dc.publisher | Wiley Periodiocals, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Chemical Engineering | en_US |
dc.title | A study of consecutive competitive reaction systems | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | The University of Michigan, Ann Arbor, Michigan | en_US |
dc.contributor.affiliationum | The University of Michigan, Ann Arbor, Michigan | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/37325/1/690080503_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/aic.690080503 | en_US |
dc.identifier.source | AIChE Journal | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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