Ab initio-based vibrational analysis of α-poly( L -alanine)
dc.contributor.author | Lee, Sang-Ho | en_US |
dc.contributor.author | Krimm, Samuel | en_US |
dc.date.accessioned | 2006-04-28T16:28:53Z | |
dc.date.available | 2006-04-28T16:28:53Z | |
dc.date.issued | 1998-10-15 | en_US |
dc.identifier.citation | Lee, Sang-Ho; Krimm, Samuel (1998)."Ab initio-based vibrational analysis of α-poly( L -alanine)." Biopolymers 46(5): 283-317. <http://hdl.handle.net/2027.42/37875> | en_US |
dc.identifier.issn | 0006-3525 | en_US |
dc.identifier.issn | 1097-0282 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/37875 | |
dc.description.abstract | Polarized ir and Raman spectra have been obtained on oriented films of α-helical poly( L -alanine) (α-PLA) and its N-deuterated derivative. These improved spectra permit a more complete assignment of observed bands to A-, E 1 -, and E 2 -species modes. A new empirical force field has been refined, based on ab initio force fields of N-methylacetamide and L -alanyl- L -alanine, which reproduces observed frequencies above 200 cm −1 to less than 5 cm −1 . A new transition dipole coupling treatment avoids the weak coupling and perturbation approximations, and can now account for the newly observed and reassigned amide I (E 2 ) mode. As a result of this improved force field, several other observed bands have also been reassigned. © 1998 John Wiley & Sons, Inc. Biopoly 46: 283–317, 1998 | en_US |
dc.format.extent | 459609 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Wiley Subscription Services, Inc., A Wiley Company | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Polymer and Materials Science | en_US |
dc.title | Ab initio-based vibrational analysis of α-poly( L -alanine) | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Biophysics Research Division and Department of Physics, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationum | Biophysics Research Division and Department of Physics, The University of Michigan, Ann Arbor, Michigan 48109 ; Biophysics Research Division and Department of Physics, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/37875/1/2_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(SICI)1097-0282(19981015)46:5<283::AID-BIP2>3.0.CO;2-L | en_US |
dc.identifier.source | Biopolymers | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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