Preparation and properties of silicon-containing polymer hybrids from 3-methacryloxypropyltrimethoxysilane
dc.contributor.author | Abe, Yoshimoto | en_US |
dc.contributor.author | Honda, Yuki | en_US |
dc.contributor.author | Gunji, Takahiro | en_US |
dc.date.accessioned | 2006-04-28T16:51:41Z | |
dc.date.available | 2006-04-28T16:51:41Z | |
dc.date.issued | 1998-10 | en_US |
dc.identifier.citation | Abe, Yoshimoto; Honda, Yuki; Gunji, Takahiro (1998)."Preparation and properties of silicon-containing polymer hybrids from 3-methacryloxypropyltrimethoxysilane." Applied Organometallic Chemistry 12(10-11): 749-753. <http://hdl.handle.net/2027.42/38311> | en_US |
dc.identifier.issn | 0268-2605 | en_US |
dc.identifier.issn | 1099-0739 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38311 | |
dc.description.abstract | The preparation of organic–inorganic polymer hybrids consisting of carbon–carbon and siloxane chains was investigated by radical polymerization of 3-methacryloxypropyltrimethoxysilane (MAS) followed by acid-catalyzed hydrolytic polycondensation. The condensation of poly(3-methacryloxypropyltrimethoxysilane) (S-PMA) of various molecular weights M n 14=830–12000 prepared by polyaddition provided transparent and flexible free-standing hybrid gel films. The mechanical properties of these films were highly dependent on the carbon–carbon chain length: with an increase in the carbon–carbon chain length, the elasticity of gel films increased, while the tensile strength and Young's modulus decreased. Hydrolyzability of S-PMA decreased with an increase in the carbon–carbon chain length, resulting in the formation of rubber-like films with flexibility. © 1998 John Wiley & Sons, Ltd. | en_US |
dc.format.extent | 132773 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Ltd. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Industrial Chemistry and Chemical Engineering | en_US |
dc.title | Preparation and properties of silicon-containing polymer hybrids from 3-methacryloxypropyltrimethoxysilane | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationother | Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo, 2641 Yamazaki, Noda, Chiba 278, Japan ; Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo, 2641 Yamazaki, Noda, Chiba 278, Japan | en_US |
dc.contributor.affiliationother | Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo, 2641 Yamazaki, Noda, Chiba 278, Japan | en_US |
dc.contributor.affiliationother | Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo, 2641 Yamazaki, Noda, Chiba 278, Japan | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38311/1/782_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(SICI)1099-0739(199810/11)12:10/11<749::AID-AOC782>3.0.CO;2-2 | en_US |
dc.identifier.source | Applied Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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