Surface science and stability of networks prepared from hydroxy-terminated polydimethylsiloxane and methyltriethoxysilane
dc.contributor.author | Wynne, Kenneth J. | en_US |
dc.contributor.author | Ho, T. | en_US |
dc.contributor.author | Johnston, E. E. | en_US |
dc.contributor.author | Myers, Sharon A. | en_US |
dc.date.accessioned | 2006-04-28T16:51:47Z | |
dc.date.available | 2006-04-28T16:51:47Z | |
dc.date.issued | 1998-10 | en_US |
dc.identifier.citation | Wynne, Kenneth J.; Ho, T.; Johnston, E. E.; Myers, Sharon A. (1998)."Surface science and stability of networks prepared from hydroxy-terminated polydimethylsiloxane and methyltriethoxysilane." Applied Organometallic Chemistry 12(10-11): 763-770. <http://hdl.handle.net/2027.42/38313> | en_US |
dc.identifier.issn | 0268-2605 | en_US |
dc.identifier.issn | 1099-0739 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38313 | |
dc.description.abstract | Polydimethylsiloxane (PDMS) hybrid networks have been prepared by the reaction of PDMS(OH) 2 , average molecular weight 26 14× 1410 3 , 43.6 14× 1410 3 and 58 14× 1410 3 , and methyltriethoxysilane (MeTEOS, 10–60 wt%) using a dibutyltin dilaurate or dibutyltin diacetate catalyst. By hydrolysis and homo- and co-condensation, MeTEOS forms a siliceous domain (MeSD) and acts as a crosslinker for the PDMS domain. Kinetic studies showed that high MeTEOS and catalyst concentrations and reduction of free surface area favor fast gelation and efficiency in converting MeTEOS to the MeSD. Under the water-sparse conditions utilized, cure was slow and substantial evaporative loss of MeTEOS occurred. © 1998 John Wiley & Sons, Ltd. | en_US |
dc.format.extent | 119178 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Ltd. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Industrial Chemistry and Chemical Engineering | en_US |
dc.title | Surface science and stability of networks prepared from hydroxy-terminated polydimethylsiloxane and methyltriethoxysilane | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationother | Materials Chemistry Branch, Code 6120, Naval Research Laboratory, Washington, DC 20375, USA ; Physical Science S&T Division-331, Office of Naval Research, Arlington, VA 22217-5660, USA ; Materials Chemistry Branch, Code 6120, Naval Research Laboratory, Washington, DC 20375, USA | en_US |
dc.contributor.affiliationother | Materials Chemistry Branch, Code 6120, Naval Research Laboratory, Washington, DC 20375, USA ; Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061-0212, USA | en_US |
dc.contributor.affiliationother | Materials Chemistry Branch, Code 6120, Naval Research Laboratory, Washington, DC 20375, USA ; Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061-0212, USA | en_US |
dc.contributor.affiliationother | Naval Air Warfare Center, Weapons Division, Chemistry and Materials Branch, China Lake, CA 93555, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38313/1/784_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(SICI)1099-0739(199810/11)12:10/11<763::AID-AOC784>3.0.CO;2-C | en_US |
dc.identifier.source | Applied Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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