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The reaction of sulfur with dilithio compounds. The syntheses and structures of phenanthro [1, 10-cd]-1,2-dithiole and phenanthro[4,5-cde] [1,2]dithiin
dc.contributor.authorAshe, Arthur J.en_US
dc.contributor.authorKampf, Jeffrey W.en_US
dc.contributor.authorSavla, Paresh M.en_US
dc.date.accessioned2006-04-28T17:04:39Z
dc.date.available2006-04-28T17:04:39Z
dc.date.issued1994-04en_US
dc.identifier.citationAshe, Arthur J.; Kampf, Jeff W.; Savla, Paresh M. (1994)."The reaction of sulfur with dilithio compounds. The syntheses and structures of phenanthro [1, 10-cd]-1,2-dithiole and phenanthro[4,5-cde] [1,2]dithiin." Heteroatom Chemistry 5(2): 113-119. <http://hdl.handle.net/2027.42/38566>en_US
dc.identifier.issn1042-7163en_US
dc.identifier.issn1098-1071en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/38566
dc.description.abstractThe sequential reaction of selected polycyclic aromatic hydrocarbons with butyllithium/TMEDA/hexane and sulfur allows preparation of ring-fused dithiins, dithioles, and thiophenes. In this manner, phenanthrene has been converted to phenanthro[4,5-cde][1,2]dithiin and phenanthro[1,10cd]-1,2-dithiole. Yellow crystals of the dithiin form in C2/c (#15) space group with Z = 4, a = 13.537(3) Å, b = 8.933(2) Å, c = 9.601(4) Å, and Β = 116.19 (2)°; while orange crystals of the dithiole form in P2 1 2 1 2 1 (#19) space group with Z = 4, a = 4.1507(5) Å, b = 14.436(3) Å, and c = 16.972(3) Å. Full structures have been determined for both compounds.en_US
dc.format.extent576864 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherVCH Publishers, Inc.en_US
dc.publisherWiley Periodiocals, Inc.en_US
dc.subject.otherChemistryen_US
dc.titleThe reaction of sulfur with dilithio compounds. The syntheses and structures of phenanthro [1, 10-cd]-1,2-dithiole and phenanthro[4,5-cde] [1,2]dithiinen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109–1055 ; Department of Chemistry, The University of Michigan, Ann Arbor, MI 48109–1055en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109–1055en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109–1055en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/38566/1/520050206_ftp.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1002/hc.520050206en_US
dc.identifier.sourceHeteroatom Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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