Infrared spectra of high polymers. V. Polyvinyl alcohol Presented in part at the Symposium on Molecular Structure and Spectroscopy, Columbus, Ohio, June 1956.
dc.contributor.author | Krimm, Samuel | en_US |
dc.contributor.author | Liang, C. Y. | en_US |
dc.contributor.author | Sutherland, G. B. B. M. | en_US |
dc.date.accessioned | 2006-04-28T18:07:24Z | |
dc.date.available | 2006-04-28T18:07:24Z | |
dc.date.issued | 1956-11 | en_US |
dc.identifier.citation | Krimm, S.; Liang, C. Y.; Sutherland, G. B. B. M. (1956)."Infrared spectra of high polymers. V. Polyvinyl alcohol Presented in part at the Symposium on Molecular Structure and Spectroscopy, Columbus, Ohio, June 1956. ." Journal of Polymer Science 22(101): 227-247. <http://hdl.handle.net/2027.42/38619> | en_US |
dc.identifier.issn | 0022-3832 | en_US |
dc.identifier.issn | 1542-6238 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38619 | |
dc.description.abstract | The infrared spectrum of polyvinyl alcohol has been investigated between 3600 and 70 cm. −1 . Polarization measurements on stretched specimens were made down to about 330 cm. −1 . The spectrum of a deuterated specimen (about 90% of the OH having been replaced by OD) has also been obtained. These data confirm and extend the results of previous workers. The spectrum is discussed in detail in relation to three structures for polyvinyl alcohol proposed on the basis of x-ray diffraction studies. The data definitely rule out the structure proposed by Mooney, and are most consistent with the structure proposed by Bunn. A complete assignment of the bands in the spectrum is proposed. From this analysis it appears that the existence of interaction forces between molecules can be convincingly demonstrated. The proposed assignments suggest a new interpretation of the 1326–1446 cm. −1 doublet, viz. , that these bands arise from mixed CH and OH in-plane bending vibrations. This is shown to be in agreement with the results of studies on simple alcohols. An alternative assignment for the 1144 cm. −1 band is also considered. | en_US |
dc.format.extent | 1297001 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Interscience Publishers, Inc. | en_US |
dc.publisher | Wiley Periodiocals, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Polymer and Materials Science | en_US |
dc.title | Infrared spectra of high polymers. V. Polyvinyl alcohol Presented in part at the Symposium on Molecular Structure and Spectroscopy, Columbus, Ohio, June 1956. | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Harrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan | en_US |
dc.contributor.affiliationum | Harrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan | en_US |
dc.contributor.affiliationum | Harrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38619/1/1202210106_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/pol.1956.1202210106 | en_US |
dc.identifier.source | Journal of Polymer Science | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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