Strain-induced crystallization of natural rubber. III. Reexamination of axial-stress changes during oriented crystallization of natural rubber vulcanizates
dc.contributor.author | Luch, Dan | en_US |
dc.contributor.author | Yeh, Gregory S. Y. | en_US |
dc.date.accessioned | 2006-04-28T18:09:14Z | |
dc.date.available | 2006-04-28T18:09:14Z | |
dc.date.issued | 1973-03 | en_US |
dc.identifier.citation | Luch, D.; Yeh, G. S. Y. (1973)."Strain-induced crystallization of natural rubber. III. Reexamination of axial-stress changes during oriented crystallization of natural rubber vulcanizates." Journal of Polymer Science: Polymer Physics Edition 11(3): 467-486. <http://hdl.handle.net/2027.42/38655> | en_US |
dc.identifier.issn | 0098-1273 | en_US |
dc.identifier.issn | 1542-9385 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38655 | |
dc.description.abstract | In order critically to evaluate the previous morphological interpretations of stress relaxation during oriented crystallization, a reexamination was made of the relaxation behavior of the same oriented natural rubber material used for the x-ray investigation in Part II of this series. Our results were found to be in qualitative agreement with previously published reports. Comparison of stress-relaxation rates at low temperatures for samples with strains of 200% or more with crystallization rates at room temperature by others for similar elongations indicates a dual nature in the strain-induced crystallization process. This conclusion is in full agreement with the indication of dual crystalline morphologies, namely, fibrillar and lamellar, for both electron microscopy and x-ray investigations on highly stretched samples reported in Parts I and II. Examination of stress-relaxation data in light of morphological evidence for oriented crystallization indicates that caution must be exercised in attaching morphological significance to the Avrami exponent n obtained from stress-relaxation or crystallization data. | en_US |
dc.format.extent | 1254090 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Inc. | en_US |
dc.subject.other | Physics | en_US |
dc.subject.other | Polymer and Materials Science | en_US |
dc.title | Strain-induced crystallization of natural rubber. III. Reexamination of axial-stress changes during oriented crystallization of natural rubber vulcanizates | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Departments of Chemical Engineering and Materials and Metallurgical Engineering, and Macromolecular Research Center, University of Michigan, Ann Arbor, Michigan 48104 | en_US |
dc.contributor.affiliationum | Departments of Chemical Engineering and Materials and Metallurgical Engineering, and Macromolecular Research Center, University of Michigan, Ann Arbor, Michigan 48104 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38655/1/180110306_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/pol.1973.180110306 | en_US |
dc.identifier.source | Journal of Polymer Science: Polymer Physics Edition | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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