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Polymerization of 4-vinylpyridinium salts. III. A clarification of the mechanism of spontaneous polymerization

dc.contributor.authorSalamone, J. C. (Joseph C.)en_US
dc.contributor.authorSnider, B.en_US
dc.contributor.authorFitch, W. L.en_US
dc.date.accessioned2006-04-28T18:15:08Z
dc.date.available2006-04-28T18:15:08Z
dc.date.issued1971-06en_US
dc.identifier.citationSalamone, J. C.; Snider, B.; Fitch, W. L. (1971)."Polymerization of 4-vinylpyridinium salts. III. A clarification of the mechanism of spontaneous polymerization." Journal of Polymer Science Part A-1: Polymer Chemistry 9(6): 1493-1504. <http://hdl.handle.net/2027.42/38761>en_US
dc.identifier.issn0449-296Xen_US
dc.identifier.issn1542-9350en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/38761
dc.description.abstractThe mechanism of the spontaneous polymerization of 4-vinylpyiridine on quaternization or protonation has been investigated. Results indicate that initiation is caused by the nucleophilic attack of 4-vinylpyridine on the double bond of 4-vinylpyridinium ion. It was shown that halide ions do not contribute significantly to the initiation. In the case of acid salts of 4-vinylpyridine a hydrogen-transfer polymerization occurred to give an ionene polymer with pyridinium units in the main chain. The “matrix” polymerization of 4-vinylpyridine on poly(phosphoric acid) or poly(acrylic acid) also resulted in ionene formation. Conditions under which stable 4-vinylpyridinium salts can be obtained are discussed.en_US
dc.format.extent725878 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherJohn Wiley & Sons, Inc.en_US
dc.subject.otherPhysicsen_US
dc.subject.otherPolymer and Materials Scienceen_US
dc.titlePolymerization of 4-vinylpyridinium salts. III. A clarification of the mechanism of spontaneous polymerizationen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumMacromolecular Research Center, Institute of Science and Technology, The University of Michigan, Ann Arbor, Michigan 48105 ; Polymer Science Program, Department of Chemistry, Lowell Technological Institute, Lowell, Massachusetts 01854en_US
dc.contributor.affiliationumMacromolecular Research Center, Institute of Science and Technology, The University of Michigan, Ann Arbor, Michigan 48105en_US
dc.contributor.affiliationumMacromolecular Research Center, Institute of Science and Technology, The University of Michigan, Ann Arbor, Michigan 48105en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/38761/1/150090603_ftp.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1002/pol.1971.150090603en_US
dc.identifier.sourceJournal of Polymer Science Part A-1: Polymer Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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