Polymers as Reagents in Organic Synthesis
dc.contributor.author | Overberger, Charles Gilbert | en_US |
dc.contributor.author | Sannes, K. N. | en_US |
dc.date.accessioned | 2006-04-28T18:16:47Z | |
dc.date.available | 2006-04-28T18:16:47Z | |
dc.date.issued | 1974-02 | en_US |
dc.identifier.citation | Overberger, C. G.; Sannes, K. N. (1974)."Polymers as Reagents in Organic Synthesis." Angewandte Chemie International Edition 13(2): 99-104. <http://hdl.handle.net/2027.42/38794> | en_US |
dc.identifier.issn | 0570-0833 | en_US |
dc.identifier.issn | 1521-3773 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38794 | |
dc.description.abstract | Polymeric reagents offer a range of unique advantages. Intramolecular reactions, such as the cyclization of peptides or Dieckmann cyclizations, can be brought about by attaching the reactive molecules at remote points along a polymer chain. In contrast, if the reactive molecules are anchored in close proximity on a polymeric support then intermolecular reactions occur, as demonstrated for a ketone synthesis. Apart from such proximity effects, cooperative effects can also be exploited, e.g. in the formation of a 2:1 complex of a crown ether and an alkali metal ion. The hydrolysis of an ester with polyvinylimidazole provides a detailed illustration of hydrophobic interactions. The simple separation of polymer-bound and low-molecular compounds by filtration is another significant advantage. | en_US |
dc.format.extent | 501667 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | HÜthig & Wepf Verlag | en_US |
dc.publisher | Wiley Periodiocals, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | General Chemistry | en_US |
dc.title | Polymers as Reagents in Organic Synthesis | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor. Mich. 48 104 (USA) ; Department of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor. Mich. 48 104 (USA) | en_US |
dc.contributor.affiliationum | Department of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor. Mich. 48 104 (USA) | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38794/1/197400991_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/anie.197400991 | en_US |
dc.identifier.source | Angewandte Chemie International Edition | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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