Synthesis of polyamide containing optically active thymine derivative as a grafted pendant

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dc.contributor.author Lu, C. X. en_US
dc.contributor.author Ji, Aixue en_US
dc.contributor.author Overberger, C. G. en_US
dc.date.accessioned 2006-04-28T18:18:03Z
dc.date.available 2006-04-28T18:18:03Z
dc.date.issued 1986-02 en_US
dc.identifier.citation Lu, C. X.; Ji, Aixue; Overberger, C. G. (1986)."Synthesis of polyamide containing optically active thymine derivative as a grafted pendant." Journal of Polymer Science Part A: Polymer Chemistry 24(2): 269-278. <http://hdl.handle.net/2027.42/38819> en_US
dc.identifier.issn 0887-624X en_US
dc.identifier.issn 1099-0518 en_US
dc.identifier.uri http://hdl.handle.net/2027.42/38819
dc.description.abstract A new route to polyamides containing optically active thymine groups as pendants has been established. The method is based on the grafting of (–) and (±)-2-(thymin-1-yl)propionic acid [(–) and (±) TPA] onto a polyamide containing hydroxyl groups. The hydroxy polyamide was prepared by selective N -acylation of an active diester of N -hydroxy-5-norborene-2,3-dicarboxamide (HONB), N , N '-(isophthaloyl-dioxy)-bis(5-norbornene-2,3-dicarboximide) (IPBONB), with 1,3-diamino-2-hydroxypropane (AHP). Model compounds (−) and (±)-(1,3-dibenzoylamino-2-propyl)2-(thymin-1-yl)propionate[(−) and (±) (BAPTP)] were prepared by direct, low-temperature esterification before synthesizing the polymer. en_US
dc.format.extent 457480 bytes
dc.format.extent 3118 bytes
dc.format.mimetype application/pdf
dc.format.mimetype text/plain
dc.language.iso en_US
dc.publisher John Wiley & Sons, Inc. en_US
dc.subject.other Chemistry en_US
dc.subject.other Polymer and Materials Science en_US
dc.title Synthesis of polyamide containing optically active thymine derivative as a grafted pendant en_US
dc.rights.robots IndexNoFollow en_US
dc.subject.hlbsecondlevel Chemical Engineering en_US
dc.subject.hlbtoplevel Engineering en_US
dc.description.peerreviewed Peer Reviewed en_US
dc.contributor.affiliationum Department of Chemistry and the Macromolcular Research Center, The University of Michigan, Ann Arbor, MI 48109 en_US
dc.contributor.affiliationum Department of Chemistry and the Macromolcular Research Center, The University of Michigan, Ann Arbor, MI 48109 en_US
dc.contributor.affiliationum Department of Chemistry and the Macromolcular Research Center, The University of Michigan, Ann Arbor, MI 48109 en_US
dc.description.bitstreamurl http://deepblue.lib.umich.edu/bitstream/2027.42/38819/1/080240206_ftp.pdf en_US
dc.identifier.doi http://dx.doi.org/10.1002/pola.1986.080240206 en_US
dc.identifier.source Journal of Polymer Science Part A: Polymer Chemistry en_US
dc.owningcollname Interdisciplinary and Peer-Reviewed
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