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Polymerization and conformational studies of poly( trans -3-ethyl- D and L -proline)
dc.contributor.authorTiba, Omaren_US
dc.contributor.authorOverberger, Charles Gilberten_US
dc.date.accessioned2006-04-28T18:18:17Z
dc.date.available2006-04-28T18:18:17Z
dc.date.issued1987-11en_US
dc.identifier.citationTiba, Omar; Overberger, C. G. (1987)."Polymerization and conformational studies of poly( trans -3-ethyl- D and L -proline)." Journal of Polymer Science Part A: Polymer Chemistry 25(11): 2941-2952. <http://hdl.handle.net/2027.42/38823>en_US
dc.identifier.issn0887-624Xen_US
dc.identifier.issn1099-0518en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/38823
dc.description.abstractPoly( L - trans -3-ethylproline), L -PT3EP, and poly( D - trans -3-ethylproline), D -PT3EP, were prepared by ring opening polymerization of the corresponding N -carboxyanhydrides (NCA) using triethylamine as an initiator. Using circular dichroism spectroscopy, it was shown that the incorporation of an ethyl group at the 3 position of the pyrrolidine ring caused a noticeable change in the conformational behavior of the polymer in solution. The ethyl group limited to some extent rotation of the polymer chain around the C [bond] [bond]CO bond and prevented the mutarotation between the two forms found in poly- L -proline polymers.en_US
dc.format.extent600017 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherJohn Wiley & Sons, Inc.en_US
dc.subject.otherChemistryen_US
dc.subject.otherPolymer and Materials Scienceen_US
dc.titlePolymerization and conformational studies of poly( trans -3-ethyl- D and L -proline)en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor, Michigan 48109en_US
dc.contributor.affiliationumDepartment of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor, Michigan 48109en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/38823/1/080251102_ftp.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1002/pola.1987.080251102en_US
dc.identifier.sourceJournal of Polymer Science Part A: Polymer Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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