Reactions and polymerization of 1-trityl-4-vinylimidazole
dc.contributor.author | Schiavone, R. J. | en_US |
dc.contributor.author | Overberger, Charles Gilbert | en_US |
dc.date.accessioned | 2006-04-28T18:18:45Z | |
dc.date.available | 2006-04-28T18:18:45Z | |
dc.date.issued | 1988-01 | en_US |
dc.identifier.citation | Schiavone, R. J.; Overberger, C. G. (1988)."Reactions and polymerization of 1-trityl-4-vinylimidazole." Journal of Polymer Science Part A: Polymer Chemistry 26(1): 107-115. <http://hdl.handle.net/2027.42/38832> | en_US |
dc.identifier.issn | 0887-624X | en_US |
dc.identifier.issn | 1099-0518 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38832 | |
dc.description.abstract | 1-Trityl-4-vinylimidazole was prepared by direct tritylation of 4(5)-vinylimidazole and polymerized using a free radical initiator. Poly(1-trityl-4-vinylimidazole) was hydrolyzed using aqueous acetic acid to give poly[4(5)-vinylimidazole]. The poly[4(5)-vinylimidazole], which was obtained from the hydrolysis of poly(1-trityl-4-vinylimidazole), was compared with poly[4(5)-vinylimidazole] prepared directly from 4(5)-vinylimidazole for differences in stereochemistry. The stereochemistry of both polymers was found to be similar by high-resolution NMR. Thus, the trityl does not influence the stereochemistry of poly[4(5)-vinylimidazole]. The reaction of 1-trityl-4-vinylimidazole with n -butyllithium gave 2-lithio-1-trityl-4-vinylimidazole. This intermediate was used to prepare 2-substituted 4(5)-vinylimidazoles, which are new monomers that can be polymerized using free radical initiators. | en_US |
dc.format.extent | 470434 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Polymer and Materials Science | en_US |
dc.title | Reactions and polymerization of 1-trityl-4-vinylimidazole | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationum | Department of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38832/1/080260111_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/pola.1988.080260111 | en_US |
dc.identifier.source | Journal of Polymer Science Part A: Polymer Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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