Heteroaromatic polyamides from cyanoimidazoles
dc.contributor.author | Allan, David S. | en_US |
dc.contributor.author | Rasmussen, Paul G. | en_US |
dc.date.accessioned | 2006-04-28T18:19:15Z | |
dc.date.available | 2006-04-28T18:19:15Z | |
dc.date.issued | 1992-06 | en_US |
dc.identifier.citation | Allan, David S.; Rasmussen, Paul G. (1992)."Heteroaromatic polyamides from cyanoimidazoles." Journal of Polymer Science Part A: Polymer Chemistry 30(7): 1413-1423. <http://hdl.handle.net/2027.42/38842> | en_US |
dc.identifier.issn | 0887-624X | en_US |
dc.identifier.issn | 1099-0518 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38842 | |
dc.description.abstract | The synthesis of a new class of heteroaromatic polyamides based on cyanoimidazoles are described. The monomer, 2-amino-4-cyanoimidazole-5-carboxylic acid ( 3 ) is prepared from a two-step hydrolysis of 2-amino-4,5-dicyanoimidazole ( 1 ). A model dimer prepared from condensation of 1 with 4-cyanoimidazole-5-carboxylic acid was structurally characterized by single crystal diffraction. The dimer, C 10 H 8 N 8 O 3 , crystallizes with Z = 2 and includes two waters of hydration in the P 1 space group, a = 7.684 (2), b = 7.864 (3), c = 10.918 (5), Α = 100.14 (3), Β = 93.15 (3), Γ = 103.79 (3). The model dimer is totally planar and shows trans geometry across the amide linkage. The monomer was polymerized by phosphorylation reaction conditions leading to a highly colored oligomeric polyamide. The polymer was characterized by IR spectroscopy, viscometry, GPC chromatography, and luminescence studies. The polymer luminesces strongly under 450 nm laser irradiation at low temperatures. | en_US |
dc.format.extent | 805667 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | John Wiley & Sons, Inc. | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Polymer and Materials Science | en_US |
dc.title | Heteroaromatic polyamides from cyanoimidazoles | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Macromolecular Science and Engineering Program, The University of Michigan, Ann Arbor, Michigan 48109-1055 | en_US |
dc.contributor.affiliationum | Macromolecular Science and Engineering Program, The University of Michigan, Ann Arbor, Michigan 48109-1055 ; Macromolecular Science and Engineering Program, The University of Michigan, Ann Arbor, Michigan 48109-1055 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38842/1/080300721_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/pola.1992.080300721 | en_US |
dc.identifier.source | Journal of Polymer Science Part A: Polymer Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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