Intermediates in the Catalytic Dehydrogenative Coupling of Arylgermanes
dc.contributor.author | Bender, John E. | en_US |
dc.contributor.author | Litz, Kyle E. | en_US |
dc.contributor.author | Giarikos, Dimitrios | en_US |
dc.contributor.author | Wells, Norman J. | en_US |
dc.contributor.author | Banaszak Holl, Mark M. | en_US |
dc.contributor.author | Kampf, Jeffrey W. | en_US |
dc.date.accessioned | 2006-04-28T18:21:12Z | |
dc.date.available | 2006-04-28T18:21:12Z | |
dc.date.issued | 1997-11 | en_US |
dc.identifier.citation | Bender, John E.; Litz, Kyle E.; Giarikos, Dimitrios; Wells, Norman J.; Banaszak Holl, Mark M.; Kampf, Jeff W. (1997)."Intermediates in the Catalytic Dehydrogenative Coupling of Arylgermanes." Chemistry - A European Journal 3(11): 1793-1796. <http://hdl.handle.net/2027.42/38880> | en_US |
dc.identifier.issn | 0947-6539 | en_US |
dc.identifier.issn | 1521-3765 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/38880 | |
dc.description.abstract | The use of a new electron-withdrawing germane, H 2 Ge[3,5-(CF 3 ) 2 C6H 3 ] 2 ( 3 ), has facilitated the isolation and characterization of three new complexes implicated in the dehydrogenative coupling of bisarylgermanes by Pt 0 -phos-phane complexes. The intermediates include a digermyl species, trans -[(Et 3 P) 2 Pt{GeH(Ar) 2 } 2 ] ( 7 ), a bound digermane showing the first stage of Ge-Ge catenation, cis -[(Et 3 P) 2 Pt(H){Ge(Ar) 2 -GeH(Ar) 2 }] ( 8 ), and the Ge-H activated form of this product, [(Et 3 P) 2 HPtGe(Ar) 2 -Ge(Ar) 2 PtH(PEt 3 ) 2 ] ( 6 ). Complexes such as 6 and 8 have not previously been isolated as intermediates in dehydrogenative coupling reactions. An X-ray crystal structure was determined for complex 6 , confirming the cis geometry of the hydrogen and germanium ligands; this provides yet another example of the stability of germyl hydrides towards reductive elimination. A similar cis geometry was observed for complex 8 . Performing the dehydrogenative coupling reaction under a CO 2 atmosphere failed to yield any products containing trapped germylene species. | en_US |
dc.format.extent | 453898 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | WILEY-VCH Verlag | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | General Chemistry | en_US |
dc.title | Intermediates in the Catalytic Dehydrogenative Coupling of Arylgermanes | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Chemistry Department, University of Michigan Ann Arbor, MI 48109-1055 (USA) Fax: Int. code +313-763-2307 | en_US |
dc.contributor.affiliationum | Chemistry Department, University of Michigan Ann Arbor, MI 48109-1055 (USA) Fax: Int. code +313-763-2307 ; Chemistry Department, University of Michigan Ann Arbor, MI 48109-1055 (USA) Fax: Int. code +313-763-2307 | en_US |
dc.contributor.affiliationum | Chemistry Department, University of Michigan Ann Arbor, MI 48109-1055 (USA) Fax: Int. code +313-763-2307 | en_US |
dc.contributor.affiliationother | Chemistry Department, Brown University Providence, RI 02912 (USA) | en_US |
dc.contributor.affiliationother | Chemistry Department, Baldwin-Wallace College Berea, OH 44017 (USA) | en_US |
dc.contributor.affiliationother | Chemistry Department, Baldwin-Wallace College Berea, OH 44017 (USA) ; Chemistry Department, Baldwin-Wallace College Berea, OH 44017 (USA) | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/38880/1/19970031110_ftp.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1002/(ISSN)1521-3765 | en_US |
dc.identifier.source | Chemistry - A European Journal | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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