Quantitative predictions of linear viscoelastic rheological properties of entangled polymers
dc.contributor.author | Pattamaprom, Cattaleeya | en_US |
dc.contributor.author | Larson, Ronald G. | en_US |
dc.contributor.author | Van Dyke, Timothy J. | en_US |
dc.date.accessioned | 2006-09-08T20:04:56Z | |
dc.date.available | 2006-09-08T20:04:56Z | |
dc.date.issued | 2000-11 | en_US |
dc.identifier.citation | Pattamaprom, Cattaleeya; Larson, Ronald G.; Van Dyke, Timothy J.; (2000). "Quantitative predictions of linear viscoelastic rheological properties of entangled polymers." Rheologica Acta 39(6): 517-531. <http://hdl.handle.net/2027.42/42204> | en_US |
dc.identifier.issn | 0035-4511 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/42204 | |
dc.description.abstract | The “dual constraint” model developed by Mead, Van Dyke et al. is here extended by inclusion of “early-time” contour-length fluctuations and constraint-release Rouse relaxation, and then evaluated by comparing its predictions with literature data for over 50 different linear and star polymers. By combining the reptation model of Doi and Edwards with contour-length fluctuations and constraint release, the model provides a systematic approach to prediction of the rheological properties of polymers. The parameters are taken from the literature and used consistently for linear polymers, star polymers, and their mixtures having the same chemical compositions. In most cases, the predictions of the model appears to agree well with data for monodisperse, bidisperse, and polydisperse linear and star polymers, except at low molecular weights. | en_US |
dc.format.extent | 450548 bytes | |
dc.format.extent | 3115 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Springer-Verlag; Springer-Verlag Berlin Heidelberg | en_US |
dc.subject.other | Constraint Release | en_US |
dc.subject.other | Linear Polymers | en_US |
dc.subject.other | Key Words Linear Viscoelastic | en_US |
dc.subject.other | Double Reptation | en_US |
dc.subject.other | Legacy | en_US |
dc.subject.other | Star Polymers | en_US |
dc.title | Quantitative predictions of linear viscoelastic rheological properties of entangled polymers | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering University of Michigan Ann Arbor, MI 48109, USA e-mail: rlarson@engin.umich.edu, US | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering University of Michigan Ann Arbor, MI 48109, USA e-mail: rlarson@engin.umich.edu, US | en_US |
dc.contributor.affiliationother | Department of Mechanical and Aerospace Engineering University of California at San Diego, | en_US |
dc.contributor.affiliationumcampus | Ann Arbor | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/42204/1/397-39-6-517_00390517.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1007/s003970000104 | en_US |
dc.identifier.source | Rheologica Acta | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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