Band-selective hetero- and homonuclear cross-polarization using trains of shaped pulses
dc.contributor.author | Zuiderweg, Erik R. P. | en_US |
dc.contributor.author | Zeng, Lei | en_US |
dc.contributor.author | Brutscher, Bernhard | en_US |
dc.contributor.author | Morshauser, Robert C. | en_US |
dc.date.accessioned | 2006-09-08T21:01:04Z | |
dc.date.available | 2006-09-08T21:01:04Z | |
dc.date.issued | 1996-09 | en_US |
dc.identifier.citation | Zuiderweg, Erik R. P.; Zeng, Lei; Brutscher, Bernhard; Morshauser, Robert C.; (1996). "Band-selective hetero- and homonuclear cross-polarization using trains of shaped pulses." Journal of Biomolecular NMR 8(2): 147-160. <http://hdl.handle.net/2027.42/43054> | en_US |
dc.identifier.issn | 0925-2738 | en_US |
dc.identifier.issn | 1573-5001 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/43054 | |
dc.description.abstract | The performance of solution cross-polarization using trains of shaped pulses on two channels is investigated by computer simulation and experiment. It is determined that a Waltz modulation pattern of Gaussian pulses of individual flip angles of 225°, issued to two coupled spins simulatneously, yields excellent coherence transfer with good phasing behavior. Simulations and experimental verification were carried out for both heteronuclear cross-polarization between two restricted areas (e.g. 1 H α − 13 C α ) and for homonuclear cross-polarization between two spectral regions (e.g. 13 CO− 13 C α ). It is shown that shaped cross-polarization behaves as pure heteronuclear cross-polarization when the two radiofrequency (rf) fields are far apart, while it behaves in some aspects analogous to homonuclear cross-polarization when the two rf fields approach each other. The novel coherence-transfer sequence, referred to as ‘cosine-modulated shaped Waltz’ (CSW), was implemented in a 3D (H)C(CCO)NH experiment using an 18-kDa isotopically labeled protein. | en_US |
dc.format.extent | 1102578 bytes | |
dc.format.extent | 3115 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | ESCOM Science Publishers B.V., Leiden/Kluwer Academic Publishers; ESCOM Science Publishers B.V. ; Springer Science+Business Media | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Polymer Sciences | en_US |
dc.subject.other | Animal Anatomy / Morphology / Histology | en_US |
dc.subject.other | TOCSY | en_US |
dc.subject.other | Hartmann-Hahn | en_US |
dc.subject.other | Protein Side-chain Assignments | en_US |
dc.subject.other | Triple-resonance | en_US |
dc.title | Band-selective hetero- and homonuclear cross-polarization using trains of shaped pulses | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Natural Resources and Environment | en_US |
dc.subject.hlbsecondlevel | Molecular, Cellular and Developmental Biology | en_US |
dc.subject.hlbsecondlevel | Ecology and Evolutionary Biology | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Biophysics Research Division, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA; Department of Biological Chemistry, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA | en_US |
dc.contributor.affiliationum | Biophysics Research Division, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA; Department of Biological Chemistry, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA | en_US |
dc.contributor.affiliationum | Biophysics Research Division, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA; Department of Biological Chemistry, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA; Institut de Biologie Structurale-Jean-Pierre Ebel, Grenoble, France | en_US |
dc.contributor.affiliationum | Biophysics Research Division, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA; Department of Biological Chemistry, The University of Michigan, 930 North University Avenue, 48109, Ann Arbor, MI, USA | en_US |
dc.contributor.affiliationumcampus | Ann Arbor | en_US |
dc.identifier.pmid | 22911139 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/43054/1/10858_2004_Article_BF00211161.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1007/BF00211161 | en_US |
dc.identifier.source | Journal of Biomolecular NMR | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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