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Advantages to Conversion of Lattice Heat Capacity to C v in the Resolution of Excess Properties The Ln 2 S 3 's as an example

dc.contributor.authorDemlow, A. R.en_US
dc.contributor.authorEldred, D. V.en_US
dc.contributor.authorJohnson, David A.en_US
dc.contributor.authorWestrum, Edgar F. Jr.en_US
dc.date.accessioned2006-09-08T21:06:56Z
dc.date.available2006-09-08T21:06:56Z
dc.date.issued1998-01en_US
dc.identifier.citationDemlow, A. R.; Eldred, D. V.; Johnson, D. A.; Westrum, E. F.; (1998). "Advantages to Conversion of Lattice Heat Capacity to C v in the Resolution of Excess Properties The Ln 2 S 3 's as an example." Journal of Thermal Analysis and Calorimetry 52(3): 1055-1062. <http://hdl.handle.net/2027.42/43143>en_US
dc.identifier.issn1418-2874en_US
dc.identifier.issn1572-8943en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/43143
dc.description.abstractThis paper represents a fitting (modeling) of the temperature dependence of the Komada-Westrum characteristic temperature for those γ-, δ- and ε-phase lanthanide sesquisulfides for which the total heat capacities, including internal degrees of freedom (e.g., Schottky and magnetic contributions), were connected to the residue of only lattice vibrations yielding lattice heat-capacity contributions. These characterittic temperatures (θ KW ) at 298.15 K are seen to behave smoothly (nearly linearly) as a function of (cationic) atomic number within the region of stability of each phase as does the density. The trends between the phases also show some consistency but not predictability of one from the other.en_US
dc.format.extent347891 bytes
dc.format.extent3115 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherKluwer Academic Publishers; Springer Science+Business Mediaen_US
dc.subject.otherChemistryen_US
dc.subject.otherInorganic Chemistryen_US
dc.subject.otherPhysical Chemistryen_US
dc.subject.otherPolymer Sciencesen_US
dc.subject.otherMeasurement Science, Instrumentationen_US
dc.subject.otherC Pen_US
dc.subject.otherC Ven_US
dc.subject.otherEntropiesen_US
dc.subject.otherLn 2 S 3en_US
dc.subject.otherPhonon Dispersionen_US
dc.titleAdvantages to Conversion of Lattice Heat Capacity to C v in the Resolution of Excess Properties The Ln 2 S 3 's as an exampleen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI, 48109-1055, USAen_US
dc.contributor.affiliationotherDepartment of Mathematics, Cornell University, Ithaca, NY, 14853en_US
dc.contributor.affiliationotherDepartment of Chemistry, Spring Arbor College, Spring Arbor, MI, 49283en_US
dc.contributor.affiliationotherDepartment of Chemistry, Spring Arbor College, Spring Arbor, MI, 49283en_US
dc.contributor.affiliationumcampusAnn Arboren_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/43143/1/10973_2004_Article_189214.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1023/A:1010153110658en_US
dc.identifier.sourceJournal of Thermal Analysis and Calorimetryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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