Advantages to Conversion of Lattice Heat Capacity to C v in the Resolution of Excess Properties The Ln 2 S 3 's as an example
dc.contributor.author | Demlow, A. R. | en_US |
dc.contributor.author | Eldred, D. V. | en_US |
dc.contributor.author | Johnson, David A. | en_US |
dc.contributor.author | Westrum, Edgar F. Jr. | en_US |
dc.date.accessioned | 2006-09-08T21:06:56Z | |
dc.date.available | 2006-09-08T21:06:56Z | |
dc.date.issued | 1998-01 | en_US |
dc.identifier.citation | Demlow, A. R.; Eldred, D. V.; Johnson, D. A.; Westrum, E. F.; (1998). "Advantages to Conversion of Lattice Heat Capacity to C v in the Resolution of Excess Properties The Ln 2 S 3 's as an example." Journal of Thermal Analysis and Calorimetry 52(3): 1055-1062. <http://hdl.handle.net/2027.42/43143> | en_US |
dc.identifier.issn | 1418-2874 | en_US |
dc.identifier.issn | 1572-8943 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/43143 | |
dc.description.abstract | This paper represents a fitting (modeling) of the temperature dependence of the Komada-Westrum characteristic temperature for those γ-, δ- and ε-phase lanthanide sesquisulfides for which the total heat capacities, including internal degrees of freedom (e.g., Schottky and magnetic contributions), were connected to the residue of only lattice vibrations yielding lattice heat-capacity contributions. These characterittic temperatures (θ KW ) at 298.15 K are seen to behave smoothly (nearly linearly) as a function of (cationic) atomic number within the region of stability of each phase as does the density. The trends between the phases also show some consistency but not predictability of one from the other. | en_US |
dc.format.extent | 347891 bytes | |
dc.format.extent | 3115 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Kluwer Academic Publishers; Springer Science+Business Media | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Inorganic Chemistry | en_US |
dc.subject.other | Physical Chemistry | en_US |
dc.subject.other | Polymer Sciences | en_US |
dc.subject.other | Measurement Science, Instrumentation | en_US |
dc.subject.other | C P | en_US |
dc.subject.other | C V | en_US |
dc.subject.other | Entropies | en_US |
dc.subject.other | Ln 2 S 3 | en_US |
dc.subject.other | Phonon Dispersion | en_US |
dc.title | Advantages to Conversion of Lattice Heat Capacity to C v in the Resolution of Excess Properties The Ln 2 S 3 's as an example | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI, 48109-1055, USA | en_US |
dc.contributor.affiliationother | Department of Mathematics, Cornell University, Ithaca, NY, 14853 | en_US |
dc.contributor.affiliationother | Department of Chemistry, Spring Arbor College, Spring Arbor, MI, 49283 | en_US |
dc.contributor.affiliationother | Department of Chemistry, Spring Arbor College, Spring Arbor, MI, 49283 | en_US |
dc.contributor.affiliationumcampus | Ann Arbor | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/43143/1/10973_2004_Article_189214.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1023/A:1010153110658 | en_US |
dc.identifier.source | Journal of Thermal Analysis and Calorimetry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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