Fractal chemical kinetics: Reacting random walkers

Abstract

Computer simulations on binary reactions of random walkers ( A + A → A ) on fractal spaces bear out a recent conjecture: ( ρ −1 − ρ 0 −1 ) ∞ t f , where ρ is the instantaneous walker density and ρ 0 the initial one, and f = d s /2, where d s is the spectral dimension. For the Sierpinski gaskets: d =2, 2 f =1.38 ( d s =1.365); d =3, 2 f =1.56 ( d s =1.547); biased initial random distributions are compared to unbiased ones. For site percolation: d = 2, p =0.60, 2 f = 1.35 ( d s =1.35); d=3, p =0.32, 2 f =1.37 ( d s =1.4); fractal-to-Euclidean crossovers are also observed. For energetically disordered lattices, the effective 2 f (from reacting walkers) and d s (from single walkers) are in good agreement, in both two and three dimensions.