Phase relations inferred from field data for mn pyroxenes and pyroxenoids
dc.contributor.author | Brown, Philip E. | en_US |
dc.contributor.author | Peacor, Donald R. | en_US |
dc.contributor.author | Essene, Eric J. | en_US |
dc.date.accessioned | 2006-09-11T18:51:18Z | |
dc.date.available | 2006-09-11T18:51:18Z | |
dc.date.issued | 1980-12 | en_US |
dc.identifier.citation | Brown, Philip E.; Essene, Eric J.; Peacor, Donald R.; (1980). "Phase relations inferred from field data for mn pyroxenes and pyroxenoids." Contributions to Mineralogy and Petrology 74(4): 417-425. <http://hdl.handle.net/2027.42/47332> | en_US |
dc.identifier.issn | 1432-0967 | en_US |
dc.identifier.issn | 0010-7999 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/47332 | |
dc.description.abstract | Electron microprobe analysis of manganese silicates from Balmat, N.Y., has helped elucidate phase relations for Mn-bearing pyroxenes and pyroxenoids. A compilation of these data along with published and unpublished analyses for phases plotting on the CaSiO 3 -MgSiO 3 -MnSiO 3 and CaSiO 3 -FeSiO 3 -MnSiO 3 faces of the RSiO 3 tetrahedron has constrained the subsolidus phase relations. For the system CaSiO 3 -FeSiO 3 -MnSiO 3 , the compositional gaps between bustamite/hedenbergite, bustamite/ rhodonite and rhodonite/pyroxmangite are constrained for middle-upper amphibolite facies conditions and extensive solid solutions limit possible three phase fields. For the CaSiO 3 -MgSiO 3 -MnSiO 3 system much less data are available but it is clear that the solid solutions are much more limited for the pyroxenoid structures and a continuum of compositions is inferred for clinopyroxenes from diopside to kanoite (MnMgSi 2 O 6 ) for amphibolite facies conditions ( T =650° C). At lower temperatures, Balmat kanoites are unstable and exsolve into C2 / c calciumrich (Ca 0.68 Mn 0.44 Mg 0.88 Si 2 O 6 ) and C2 / c calciumpoor (Ca 0.12 Mn 1.02 Mg 0.86 Si 2 O 6 ) phases. At temperatures of 300–400° C the calcium-poor phase subsequently has undergone a transformation to a P 2 1 / c structure; this exsolution-inversion relationship is analogous to that relating augites and pigeonites in the traditional pyroxene quadrilateral. Rhodonite coexisting with Mn-clinopyroxenes is compositionally restricted to Mn 0.75–0.95 Mg 0.0–0.15 Ca 0.05–0.13 SiO 3 . For the original pyroxene+rhodonite assemblage, the Mg and Ca contents of the rhodonite are fixed for a specific P (6kbars)- T (650° C)- X (H 2 O)- X (CO 2 ) by the coexistence of talc+quartz and calcite+quartz respectively. | en_US |
dc.format.extent | 933030 bytes | |
dc.format.extent | 3115 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Springer-Verlag | en_US |
dc.subject.other | Mineralogy | en_US |
dc.subject.other | Mineral Resources | en_US |
dc.subject.other | Geology | en_US |
dc.subject.other | Geosciences | en_US |
dc.title | Phase relations inferred from field data for mn pyroxenes and pyroxenoids | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Geology and Earth Sciences | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Geological Sciences, The University of Michigan, 48109, Ann Arbor, MI, USA | en_US |
dc.contributor.affiliationum | Department of Geological Sciences, The University of Michigan, 48109, Ann Arbor, MI, USA; U.S. Geological Survey, 959 National Center, 22092, Reston, VA, USA | en_US |
dc.contributor.affiliationum | Department of Geological Sciences, The University of Michigan, 48109, Ann Arbor, MI, USA | en_US |
dc.contributor.affiliationumcampus | Ann Arbor | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/47332/1/410_2004_Article_BF00518121.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1007/BF00518121 | en_US |
dc.identifier.source | Contributions to Mineralogy and Petrology | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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