View Item 

Show simple item record

Assessing Guest Selectivity within Metallacrown Host Compartments
dc.contributor.authorLim, Choong-Sunen_US
dc.contributor.authorVan Noord, Annabel Cutlanden_US
dc.contributor.authorKampf, Jeffrey W.en_US
dc.contributor.authorPecoraro, Vincent L.en_US
dc.date.accessioned2007-09-20T18:33:51Z
dc.date.available2008-09-08T14:25:14Zen_US
dc.date.issued2007-04en_US
dc.identifier.citationLim, Choong-Sun; Van Noord, Annabel Cutland; Kampf, Jeff W.; Pecoraro, Vincent L. (2007)."Assessing Guest Selectivity within Metallacrown Host Compartments." European Journal of Inorganic Chemistry 2007(10): 1347-1350. <http://hdl.handle.net/2027.42/56027>en_US
dc.identifier.issn1434-1948en_US
dc.identifier.issn1099-0682en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/56027
dc.description.abstract15-MC-5 complexes associate in the solid state to form chiral compartments capable of binding guests. Using small molecular yardsticks, we are able to assess the size restrictions of these structures. Dicarboxylate guests that are too short to span the Gd III ions are stabilized by solvates that hydrogen bond to the uncoordinated carboxylate, while guests that are too long destroy the weakly associated structure. We also demonstrate that all that is required for guest encapsulation is unsaturation of the chain connection carboxylates rather than necessitating the presence of aromaticity. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)en_US
dc.format.extent158983 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.publisherWILEY-VCH Verlagen_US
dc.subject.otherChemistryen_US
dc.subject.otherGeneral Chemistryen_US
dc.titleAssessing Guest Selectivity within Metallacrown Host Compartmentsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry and Biophysics Research Division, The University of Michigan, Ann Arbor, Michigan 48109-1055, USA, Fax: +1-17349367628en_US
dc.contributor.affiliationumDepartment of Chemistry and Biophysics Research Division, The University of Michigan, Ann Arbor, Michigan 48109-1055, USA, Fax: +1-17349367628en_US
dc.contributor.affiliationumDepartment of Chemistry and Biophysics Research Division, The University of Michigan, Ann Arbor, Michigan 48109-1055, USA, Fax: +1-17349367628en_US
dc.contributor.affiliationumDepartment of Chemistry and Biophysics Research Division, The University of Michigan, Ann Arbor, Michigan 48109-1055, USA, Fax: +1-17349367628 ;en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/56027/1/1347_ftp.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1002/ejic.200700054en_US
dc.identifier.sourceEuropean Journal of Inorganic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


Files in this item

Name:
1347_ftp.pdf
Size:
155.2KB
Format:
PDF
View/Open

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.