Green Medium for the Hydrolysis of 5-Cyanovaleramide
dc.contributor.author | Duan, P. -G. | en_US |
dc.contributor.author | Li, Shuang | en_US |
dc.contributor.author | Yang, Yan | en_US |
dc.contributor.author | Wang, Zhi-Zhong | en_US |
dc.date.accessioned | 2009-05-04T18:26:50Z | |
dc.date.available | 2010-07-06T14:30:32Z | en_US |
dc.date.issued | 2009-05 | en_US |
dc.identifier.citation | Duan, P.-G.; Li, S.; Yang, Y.; Wang, Z.-Z. (2009). "Green Medium for the Hydrolysis of 5-Cyanovaleramide." Chemical Engineering & Technology - CET 32(5): 771-777. <http://hdl.handle.net/2027.42/62148> | en_US |
dc.identifier.issn | 0930-7516 | en_US |
dc.identifier.issn | 1521-4125 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/62148 | |
dc.description.abstract | Hydrolysis of 5-cyanovaleramide (5-CVAM) in near-critical water without the addition of any catalyst has been demonstrated. The results demonstrated that the cyano group at one end of the carbon of 5-CVAM is more reactive than the amide group at the other end, under the same experimental conditions. The relations between 5-CVAM concentration and residence time revealed that hydrolysis of 5-CVAM shows second-order reaction kinetics in the investigated temperature range. The rate constants, average apparent activation energy and pre-exponential factor were evaluated according to the Arrhenius equation. Based on the experimental results, a carbon balance was calculated, and a hydrolysis reaction scheme of 5-CVAM was proposed. | en_US |
dc.format.extent | 181556 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.publisher | WILEY-VCH Verlag | en_US |
dc.subject.other | Chemistry | en_US |
dc.subject.other | Industrial Chemistry and Chemical Engineering | en_US |
dc.title | Green Medium for the Hydrolysis of 5-Cyanovaleramide | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Shanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. China ; Department of Chemical Engineering, The University of Michigan, Ann Arbor, USA | en_US |
dc.contributor.affiliationother | Shanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. China | en_US |
dc.contributor.affiliationother | Shanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. China | en_US |
dc.contributor.affiliationother | Shanghai Key Laboratory of Green Chemistry and Green Process, Department of Chemistry, East China Normal University, Shanghai, P.R. China | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/62148/1/771_ftp.pdf | |
dc.identifier.doi | 10.1002/ceat.200800607 | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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