A route to high surface area, porosity and inclusion of large molecules in crystals
dc.contributor.author | Chae, Hee. K. | en_US |
dc.contributor.author | Siberio-Perez, D. Y. | en_US |
dc.contributor.author | Kim, J. | en_US |
dc.contributor.author | Go, Y. | en_US |
dc.contributor.author | Eddaoudi, M. | en_US |
dc.contributor.author | Matzger, A. J. | en_US |
dc.contributor.author | O'Keeffe, M. | en_US |
dc.contributor.author | Yaghi, Omar M. | en_US |
dc.date.accessioned | 2009-06-01T17:26:31Z | |
dc.date.available | 2009-06-01T17:26:31Z | |
dc.date.issued | 2004-02-05 | en_US |
dc.identifier.citation | Chae, HK; Siberio-Perez, DY; Kim, J; Go, Y; Eddaoudi, M; Matzger, AJ; O'Keeffe, M; Yaghi, OM. (2004) "A route to high surface area, porosity and inclusion of large molecules in crystals." Nature 427(6974): 523-527. <http://hdl.handle.net/2027.42/62609> | en_US |
dc.identifier.issn | 0028-0836 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/62609 | |
dc.identifier.uri | http://www.ncbi.nlm.nih.gov/sites/entrez?cmd=retrieve&db=pubmed&list_uids=14765190&dopt=citation | en_US |
dc.description.abstract | One of the outstanding challenges in the field of porous materials is the design and synthesis of chemical structures with exceptionally high surface areas(1). Such materials are of critical importance to many applications involving catalysis, separation and gas storage. The claim for the highest surface area of a disordered structure is for carbon, at 2,030 m(2) g(-1) (ref. 2). Until recently, the largest surface area of an ordered structure was that of zeolite Y, recorded at 904 m(2) g(-1) (ref. 3). But with the introduction of metal-organic framework materials, this has been exceeded, with values up to 3,000 m(2) g(-1) (refs 4-7). Despite this, no method of determining the upper limit in surface area for a material has yet been found. Here we present a general strategy that has allowed us to realize a structure having by far the highest surface area reported to date. We report the design, synthesis and properties of crystalline Zn4O(1,3,5-benzenetribenzoate)(2), a new metal-organic framework with a surface area estimated at 4,500 m(2) g(-1). This framework, which we name MOF-177, combines this exceptional level of surface area with an ordered structure that has extra-large pores capable of binding polycyclic organic guest molecules-attributes not previously combined in one material. | en_US |
dc.format.extent | 310812 bytes | |
dc.format.extent | 2489 bytes | |
dc.format.mimetype | application/octet-stream | |
dc.format.mimetype | text/plain | |
dc.publisher | Nature Publishing Group | en_US |
dc.source | Nature | en_US |
dc.title | A route to high surface area, porosity and inclusion of large molecules in crystals | en_US |
dc.type | Article | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA | en_US |
dc.contributor.affiliationother | Arizona State Univ, Dept Chem, Tempe, AZ 85287 USA | en_US |
dc.contributor.affiliationother | Hankuk Univ Foreign Studies, Dept Chem, Seoul, South Korea | en_US |
dc.identifier.pmid | 14765190 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/62609/1/nature02311.pdf | |
dc.identifier.doi | http://dx.doi.org/10.1038/nature02311 | en_US |
dc.identifier.source | Nature | en_US |
dc.contributor.authoremail | matzger@umich.edu; mokeeffe@asu.edu; oyaghi@umich.edu | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.