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Ketone Hydrosilylation with Sugar Silanes Followed by Intramolecular Aglycone Delivery: An Orthogonal Glycosylation Strategy

dc.contributor.authorBuchan, Zachary Allenen_US
dc.contributor.authorBader, Scott J.en_US
dc.contributor.authorMontgomery, Johnen_US
dc.date.accessioned2009-07-06T15:38:11Z
dc.date.available2010-08-02T17:56:56Zen_US
dc.date.issued2009-06-15en_US
dc.identifier.citationBuchan, Zachary 14A.; Bader, Scott 14J.; Montgomery, John (2009). "Ketone Hydrosilylation with Sugar Silanes Followed by Intramolecular Aglycone Delivery: An Orthogonal Glycosylation Strategy We acknowledge support from the National Institutes of Health (GM 57014) and from Thermo Fisher for a pilot project grant administered by the University of Michigan Life Sciences Institute. ." Angewandte Chemie 121(26): 4934-4938. <http://hdl.handle.net/2027.42/63053>en_US
dc.identifier.issn0044-8249en_US
dc.identifier.issn1521-3757en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/63053
dc.description.abstractSÜßer Anhang nach Wunsch : Ein Verfahren zur direkten Glycosylierung von Ketonen ohne Hydroxyintermediate ermÖglicht die ortsselektive Glycosylierung von Hydroxyketonen an der Keton- oder der Alkoholeinheit, ohne dass Schutzgruppen am Aglycon notwendig sind (siehe Schema). Die OrtsselektivitÄt wird in den Hydrosilylierungen und dehydrierenden Silylierungen mit Zuckersilanen durch die Katalysatorstruktur bestimmt. Bn=Benzyl.en_US
dc.format.extent364547 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.publisherWILEY-VCH Verlagen_US
dc.subject.otherChemistryen_US
dc.subject.otherGeneral Chemistryen_US
dc.titleKetone Hydrosilylation with Sugar Silanes Followed by Intramolecular Aglycone Delivery: An Orthogonal Glycosylation Strategyen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (USA), Fax: (+1) 734-763-1106, http://www.umich.edu/∼jmgroupen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (USA), Fax: (+1) 734-763-1106, http://www.umich.edu/∼jmgroupen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (USA), Fax: (+1) 734-763-1106, http://www.umich.edu/∼jmgroupen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/63053/1/4934_ftp.pdf
dc.identifier.doi10.1002/ange.200901666en_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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