Now showing items 11-20 of 35
Vibrational force field and normal mode analysis of N,N-dimethylacetamide
(Elsevier, 1989)
A simple general valence force field has been refined for N,N-dimethylacetamide which includes both in-plane and out-of-plane modes. This force field gives good agreement between observed and calculated frequencies for ...
Vibrational analysis of cyclo(-Ala--Ala) in two crystalline forms. Effect of structure on peptide group and CH modes
(Elsevier, 1988)
Cyclo(-Ala--Ala) has been found by X-ray diffraction to crystallize in two forms with different hydrogen bond patterns and strengths and different conformations of the C[alpha]H[alpha]C[beta]H3 group. We have done a ...
Instrumental improvements for rapid, detailed kinetic studies of oxygenase activity
(Elsevier, 1979-07-15)
The characteristics of an electronic differentiator that facilitates continuous monitoring of changes in the oxygen concentration measured by a polarographic oxygen electrode are described. In addition, some properties of ...
Surface enhanced raman spectroscopy of halide ions on colloidal silver: simulation of silver-halide ion spectra
(Elsevier, 1983-01-02)
The surface enhanced Raman spectra of halide ions adsorbed on colloidal silver surfaces can be explained by an interacting dipole model of a discrete adsorbate superlattice. Both (100) and (111) surfaces have been modeled, ...
Electromagnetic effects on a molecule at a metal surface : I. Effects of nonlocality and finite molecular size
(Elsevier, 1981-08-02)
The electromagnetic effects on a molecule near a metal surface are considered with the view to understanding the surface-enhanced-Raman-scattering (SERS) effect. The image enhancement effect is calculated including the ...
Vibrational analysis of 2,3-dichlorobutanes
(Elsevier, 1983)
Using intensity changes from liquid to solid for meso- and racemic-2,3-dichlorobutanes, and preliminary normal mode calculations based on a force field for secondary chlorides, we have been able to identify the bands ...
A valence force field for the amide group
(Elsevier, 1971-01)
A valence force field is presented for the grouping R-CO-NH-R' where R and R' are CH2 or CH3, derived from the frequencies of N-methylacetanide, nylons, and some of the deuteroderivatives. By refining all experimental data ...
Shift and broadening of the vibrational mode for a diatomic molecule adsorbed on a metal surface
(Elsevier, 1983-06-02)
The shift and broadening of the vibrational frequency of a diatomic molecule adsorbed on a metal surface are calculated on the basis of electromagnetic interactions. Finite molecular size and nonlocal metal response are ...
High resolution laser spectroscopy of relaxation and the excitation lineshape of excitons in GaAs quantum well structures
(Elsevier, 1990-04-01)
A new class of measurements on GaAs quantum well structures based on frequency domain nonlinear laser spectroscopy is described. Room temperature measurements of the excitation relaxation show an interference effect in the ...
Epitaxial growth and characterization of GaAs/Al/GaAs heterostructures
(Elsevier, 1990-04-01)
We report on transmission electron microscopy, secondary ion mass spectroscopy, X-ray and Raman scattering studies of GaAs/Al/GaAs heterostructures grown by migration enhanced epitaxy.