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Neutron Scattering in Stretch‐Oriented Polyethylene

dc.contributor.authorMyers, W.en_US
dc.contributor.authorSummerfield, G. C.en_US
dc.contributor.authorKing, John Swintonen_US
dc.date.accessioned2010-05-06T20:43:46Z
dc.date.available2010-05-06T20:43:46Z
dc.date.issued1966-01-01en_US
dc.identifier.citationMyers, W.; Summerfield, G. C.; King, J. S. (1966). "Neutron Scattering in Stretch‐Oriented Polyethylene." The Journal of Chemical Physics 44(1): 184-187. <http://hdl.handle.net/2027.42/69521>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/69521
dc.description.abstractMeasurements on stretch‐oriented polyethylene held at 100°K have been undertaken in an attempt to clearly identify the frequency limit of the calculated stretch—bend acoustic mode. A simplified ``constant‐Q'' scattering technique was used in order to isolate the longitudinal C☒C☒C motion. A frequency limit was observed at 525±15 cm−1. The persistence of the torsional mode response in the longitudinal experiment is unexpectedly large.en_US
dc.format.extent3102 bytes
dc.format.extent274055 bytes
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dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleNeutron Scattering in Stretch‐Oriented Polyethyleneen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Nuclear Engineering, The University of Michigan, Ann Arbor, Michiganen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/69521/2/JCPSA6-44-1-184-1.pdf
dc.identifier.doi10.1063/1.1726443en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceT. P. Lin and J. L. Koenig, J. Mol. Spectry. 9, 228 (1962).en_US
dc.identifier.citedreferenceM. Tasumi, T. Shimanouchi, and T. Miyazawa, J. Mol. Spectry. 9, 261 (1962).en_US
dc.identifier.citedreferenceH. R. Danner, G. H. Safford, H. Boutin, and M. Berger, J. Chem. Phys. 40, 1417 (1964).en_US
dc.identifier.citedreferenceJ. S. King and J. L. Donovan, Bull. Am. Phys. Soc. 9, 623 (1964).en_US
dc.identifier.citedreferenceH. Boutin, H. Prask, S. F. Trevino, and H. R. Danner, Inelastic Scattering Neutrons Solids Liquids, Proc, Symp. 3rd Bombay, India 1964 (to be published).en_US
dc.identifier.citedreferenceW. R. Myers, J. L. Donovan, and J. S. King, J. Chem. Phys. 42, 4299 (1965).en_US
dc.identifier.citedreferenceReference 5 contains room‐temperature data on stretched polyethylene, collected on a time‐of‐flight spectrometer. The authors made no reference to orientation.en_US
dc.identifier.citedreferenceB. N. Brockhouse, “Methods for Neutron Spectroscopy,” At. Energy Can. Ltd., Rept. No. CRNP‐947 (1961).en_US
dc.identifier.citedreferenceSee, for example, A. C. Zemach and R. J. Glauber, Phys. Rev. 101, 118 (1956).en_US
dc.identifier.citedreferenceG. C. Summerfield, J. Chem. Phys. 43, 1079 (1965).en_US
dc.identifier.citedreferenceA. Sjolander, Arkiv Fysik 14, 315 (1958).en_US
dc.identifier.citedreferenceP. H. Geil, Polymer Rev. 5, 421 (1963).en_US
dc.identifier.citedreferenceThe spectrometer has been described by J. L. Donovan, thesis, The University of Michigan, 1964.en_US
dc.identifier.citedreferenceCalculated limits are 530 cm−1530cm−1 (1), 505 cm−1505cm−1 (2), and 540 cm−1540cm−1 (private communication from C. Opaskar and S. Krimm, calculation based on the Schachtschneider and Snyder force constants).en_US
dc.identifier.citedreferenceA recent calculation for a polyethylene crystal indicates that ν5ν5 and ν9ν9 are mixtures of the skeletal deformation and torsional modes; M. Tasumi and T. Shimanouchi, J. Chem. Phys. 43, 1245 (1965).en_US
dc.owningcollnamePhysics, Department of


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