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Potential constants of borane carbonyl
dc.contributor.authorJones, Llewellyn H.en_US
dc.contributor.authorTaylor, Robert Cooperen_US
dc.contributor.authorPaine, Robert T.en_US
dc.date.accessioned2010-05-06T20:45:23Z
dc.date.available2010-05-06T20:45:23Z
dc.date.issued1979-01-15en_US
dc.identifier.citationJones, Llewellyn H.; Taylor, Robert C.; Paine, Robert T. (1979). "Potential constants of borane carbonyl." The Journal of Chemical Physics 70(2): 749-757. <http://hdl.handle.net/2027.42/69538>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/69538
dc.description.abstractThe vibrational spectra of several isotopic species of BH3CO in neon matrices at 10 °K have been observed. A number of combination bands have also been observed, leading to an assignment of most of the fundamental harmonic frequencies of these isotopic species. A least squares normal coordinate treatment, without constraints, has estimated a set of potential constants. We can conclude that the CO bond in BH3CO is slightly stronger than that of free CO. The interaction coordinates suggest that unimolecular dissociation of the B–C bond proceeds initially toward BH−3+CO+ but reverts to BH3+CO before dissociation.en_US
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dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titlePotential constants of borane carbonylen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48106en_US
dc.contributor.affiliationotherLos Alamos Scientific Laboratory, University of California, Los Alamos, New Mexico 87545en_US
dc.contributor.affiliationotherLos Alamos Scientific Laboratory, University of California, Los Alamos, New Mexico 87545en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/69538/2/JCPSA6-70-2-749-1.pdf
dc.identifier.doi10.1063/1.437505en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.identifier.citedreferenceActually, we do not know what the force constant for a good B‐C single bond should be; it may, in fact, be less than that for C‐C, C‐N, etc.en_US
dc.identifier.citedreferenceRef. 14, pp. 29–30.en_US
dc.owningcollnamePhysics, Department of


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