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Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds

dc.contributor.authorBerry, R. Stephenen_US
dc.date.accessioned2010-05-06T20:46:13Z
dc.date.available2010-05-06T20:46:13Z
dc.date.issued1960-03en_US
dc.identifier.citationBerry, R. Stephen (1960). "Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds." The Journal of Chemical Physics 32(3): 933-938. <http://hdl.handle.net/2027.42/69547>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/69547
dc.description.abstractA method is presented whereby the WKB expression for tunneling frequencies permits correlation of these frequencies for members of homologous series of molecules. The necessary data required are the tunneling rate for one member of the series, and structural parameters and vibrational frequencies for all members of interest. The method is applied to ND3, NF3, PH3, and AsH3, using NH3 as the molecule whose frequency is known. The method also is used to support the hypothesis that pseudorotation occurs in the trigonal bipyramids PF5 and PCl5.en_US
dc.format.extent3102 bytes
dc.format.extent396536 bytes
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dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleCorrelation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compoundsen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michiganen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/69547/2/JCPSA6-32-3-933-1.pdf
dc.identifier.doi10.1063/1.1730820en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.identifier.citedreferenceThe author is indebted to Dr. F. T. Smith who first pointed out to him the existence of the pseudorotation operation of a trigonal bipyramid.en_US
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dc.owningcollnamePhysics, Department of


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