Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds

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dc.contributor.author Berry, R. Stephen en_US
dc.date.accessioned 2010-05-06T20:46:13Z
dc.date.available 2010-05-06T20:46:13Z
dc.date.issued 1960-03 en_US
dc.identifier.citation Berry, R. Stephen (1960). "Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds." The Journal of Chemical Physics 32(3): 933-938. <http://hdl.handle.net/2027.42/69547> en_US
dc.identifier.uri http://hdl.handle.net/2027.42/69547
dc.description.abstract A method is presented whereby the WKB expression for tunneling frequencies permits correlation of these frequencies for members of homologous series of molecules. The necessary data required are the tunneling rate for one member of the series, and structural parameters and vibrational frequencies for all members of interest. The method is applied to ND3, NF3, PH3, and AsH3, using NH3 as the molecule whose frequency is known. The method also is used to support the hypothesis that pseudorotation occurs in the trigonal bipyramids PF5 and PCl5. en_US
dc.format.extent 3102 bytes
dc.format.extent 396536 bytes
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dc.publisher The American Institute of Physics en_US
dc.rights © The American Institute of Physics en_US
dc.title Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds en_US
dc.subject.hlbsecondlevel Physics en_US
dc.subject.hlbtoplevel Science en_US
dc.description.peerreviewed Peer Reviewed en_US
dc.contributor.affiliationum Department of Chemistry, The University of Michigan, Ann Arbor, Michigan en_US
dc.description.bitstreamurl http://deepblue.lib.umich.edu/bitstream/2027.42/69547/2/JCPSA6-32-3-933-1.pdf
dc.identifier.doi 10.1063/1.1730820 en_US
dc.identifier.source The Journal of Chemical Physics en_US
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dc.owningcollname Physics, Department of
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