A thermophysical study of the melting process in alkyl chain metal n-alkanoates: The thallium (I) series
dc.contributor.author | Cheda, J. A. R. | en_US |
dc.contributor.author | Redondo, M. I. | en_US |
dc.contributor.author | García, M. V. | en_US |
dc.contributor.author | López De La Fuente, F. L. | en_US |
dc.contributor.author | Fernández-Martín, F. | en_US |
dc.contributor.author | Westrum, Edgar F. Jr. | en_US |
dc.date.accessioned | 2010-05-06T20:51:17Z | |
dc.date.available | 2010-05-06T20:51:17Z | |
dc.date.issued | 1999-08-22 | en_US |
dc.identifier.citation | Cheda, J. A. R.; Redondo, M. I.; García, M. V.; López de la Fuente, F. L.; Fernández-Martín, F.; Westrum, E. F. (1999). "A thermophysical study of the melting process in alkyl chain metal n-alkanoates: The thallium (I) series." The Journal of Chemical Physics 111(8): 3590-3598. <http://hdl.handle.net/2027.42/69602> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/69602 | |
dc.description.abstract | The peculiar thermal behavior of the thallium(I) n-alkanoates series (consisting in several transitions between polymorphic and mesomorphic phases) in comparison with other metallic n-alkanoates series is stated. The allowance of highly accurate adiabatic heat capacity data permits a study of the CH2CH2 contributions to the lattice heat capacity curve at low temperature. Moreover, in this series an anomalous gradual enhancement of the lattice heat capacity has been interpreted from vibrational spectroscopy results as a noncooperative effect due to the internal hindered rotation of the alkyl chain (formation of gauche defects, even in the solid state). The thermodynamics of the “stepwise melting process” from the totally ordered solid at low temperature to the isotropic liquid is based on a revised lattice heat-capacity curve. This was used to evaluate the energy and entropy not only of the clear first order transitions present in the series but also of the described noncooperative effect. The CH2CH2 enthalpy and entropy contribution for this series is estimated and a comparison with the published values for other series is carried out. Moreover, the texture of the mesophases is revealed by polarized light microscopy. © 1999 American Institute of Physics. | en_US |
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dc.format.mimetype | text/plain | |
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dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | A thermophysical study of the melting process in alkyl chain metal n-alkanoates: The thallium (I) series | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055 | en_US |
dc.contributor.affiliationother | Dpto. Química-Física I, Fctd. CC. Químicas, Universtitaria Complutense, 28040 Madrid, Spain | en_US |
dc.contributor.affiliationother | Instituto del Frío (CSIC), Ciudad Universitaria, 28040 Madrid, Spain | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/69602/2/JCPSA6-111-8-3590-1.pdf | |
dc.identifier.doi | 10.1063/1.480265 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
dc.identifier.citedreference | J. J. Duruz, H. J. Michels, and A. R. Ubbelohde, Proc. R. Soc. London, Ser. A PRLAAZ322, 281 (1971). | en_US |
dc.identifier.citedreference | T. A. Mirnaya, V. D. Prisyazhny, and V. A. Shcherbakov, Russ. Chem. Rev. RCRVAB58, 821 (1989). | en_US |
dc.identifier.citedreference | J. F. Nagle, J. Chem. Phys. JCPSA658, 252 (1973). | en_US |
dc.identifier.citedreference | J. F. Nagle, Annu. Rev. Phys. Chem. ARPLAP31, 157 (1981). | en_US |
dc.identifier.citedreference | M. V. Garcia, M. I. Redondo, F. L. López de la Fuente, J. A. R. Cheda, E. F. Westrum, Jr., and F. Fernández-Martín, Appl. Spectrosc. APSPA448, 338 (1994). | en_US |
dc.identifier.citedreference | F. Fernández-Martín, F. L. López de la Fuente, and J. A. R. Cheda, Thermochim. Acta THACAS73, 109 (1984). | en_US |
dc.identifier.citedreference | J. Boerio-Goates, F. L. López de la Fuente, J. A. R. Cheda, and E. F. Westrum, Jr., J. Chem. Thermodyn. JCTDAF17, 401 (1985). | en_US |
dc.identifier.citedreference | S. P. Ngeyi, F. L. López de la Fuente, J. A. R. Cheda, F. Fernández-Martín, and E. F. Westrum, Jr., J. Chem. Thermodyn. JCTDAF17, 409 (1985). | en_US |
dc.identifier.citedreference | S. P. Ngeyi, E. F. Westrum, Jr., F. L. López de la Fuente, J. A. R. Cheda, and F. Fernández-Martín, J. Chem. Thermodyn. JCTDAF19, 327 (1987). | en_US |
dc.identifier.citedreference | F. L. López de la Fuente, E. F. Westrum, Jr., J. A. R. Cheda, and F. Fernández-Martín, J. Chem. Thermodyn. JCTDAF19, 1261 (1987). | en_US |
dc.identifier.citedreference | F. L. López de la Fuente, J. A. R. Cheda, F. Fernández-Martín, and E. F. Westrum, Jr., J. Chem. Thermodyn. JCTDAF20, 1137 (1988). | en_US |
dc.identifier.citedreference | A. R. Labban, F. L. López de la Fuente, J. A. R. Cheda, E. F. Westrum, Jr., and F. Fernández-Martín, J. Chem. Thermodyn. JCTDAF21, 375 (1989). | en_US |
dc.identifier.citedreference | M. V. Roux, C. Turrión, F. Fernández-Martín, F. L. López de la Fuente, and J. A. R. Cheda, Thermochim. Acta THACAS139, 139 (1989). | en_US |
dc.identifier.citedreference | F. Fernández-Martín, F. L. López de la Fuente, J. A. R. Cheda, and E. F. Westrum, Jr., XXI Reunión Bienal de la R. S. Española de Quimica. 1986. Santiago de Compostela (Spain). Resúmenes de Comunicaciones, p. 635. | en_US |
dc.identifier.citedreference | J. A. R. Cheda, F. Fernández-Martín, R. J. Burns, and E. F. Westrum, Jr., J. Chem. Thermodyn. JCTDAF26, 829 (1994). | en_US |
dc.identifier.citedreference | F. L. López de la Fuente, “Propiedades Termofísicas y Transiciones de Fase de n-Alcanoatos de Talio(I),” Ph.D. thesis, Universidad Complutense, Madrid, Spain, 1989, Section IV. | en_US |
dc.identifier.citedreference | J. A. R. Cheda, P. Ungarelli, F. L. López de la Fuente, F. Fernández-Martín, Y. Xu, W. L. IJdo, and E. F. Westrum, Jr., Thermochim. Acta THACAS266, 163 (1995). | en_US |
dc.identifier.citedreference | F. Fernández-Martín, J. A. R. Cheda, L. L. Jones, C. C. Lin, and E. F. Westrum, Jr., J. Chem. Thermodyn. JCTDAF26, 925 (1994). | en_US |
dc.identifier.citedreference | B. Wunderlich, M. Möller, J. Grebowicz, and H. Baur, in Conformational Motion and Disorder in Low and High Molecular Mass Crystals, edited by H. Höcker (Springer-Verlag, New York, 1988), pp. 1–6. | en_US |
dc.identifier.citedreference | J. Lindau, S. Diele, H. Kruger, and H. D. Dörfler, Z. Phys. Chem. (Leipzig) ZPCLAH262, 775 (1981). | en_US |
dc.identifier.citedreference | J. Lindau, H. J. König, and H. D. Dörfler, Colloid Polym. Sci. CPMSB6261, 236 (1983). | en_US |
dc.identifier.citedreference | R. Krombach and G. M. Schneider, J. Chem. Thermodyn. JCTDAF25, 445 (1993). | en_US |
dc.identifier.citedreference | W. B. Person and G. C. Pimentel, J. Am. Chem. Soc. JACSAT75, 532 (1953). | en_US |
dc.identifier.citedreference | M. G. Broadhurst, J. Res. Natl. Bur. Stand., Sect. A JNBAAR67, 233 (1963). | en_US |
dc.identifier.citedreference | P. Sellers, G. Stridh, and S. Sunner, J. Chem. Eng. Data JCEAAX23, 250 (1978). | en_US |
dc.identifier.citedreference | S. Sunner and C. A. Wulff, J. Chem. Thermodyn. JCTDAF12, 505 (1980). | en_US |
dc.identifier.citedreference | M. A. White, J. Chem. Phys. JCPSA681, 6100 (1984). | en_US |
dc.identifier.citedreference | S. P. Ngeyi, E. F. Westrum, Jr., and P. Franzosini, J. Chem. Thermodyn. JCTDAF18, 609 (1986). | en_US |
dc.identifier.citedreference | Y. Jin and B. Wunderlich, J. Phys. Chem. JPCHAX95, 9000 (1991). | en_US |
dc.identifier.citedreference | K. S. Pitzer, J. Chem. Phys. JCPSA68, 711 (1940), Chem. Rev. CHREAY27, 39 (1940). | en_US |
dc.identifier.citedreference | G. J. Janz, Thermodynamical Properties of Organic Compounds (Academic, New York, 1967), Chap. 3, pp. 35. | en_US |
dc.identifier.citedreference | A. Sánchez Arenas, M. V. García, M. I. Redondo, J. A. R. Cheda, M. V. Roux, and C. Turrion, Liq. Cryst. LICRE618, 431 (1995). | en_US |
dc.identifier.citedreference | H. A. Ellis, Mol. Cryst. Liq. Cryst. MCLCA5139, 281 (1986). | en_US |
dc.identifier.citedreference | A. M. Amorim da Costa, H. D. Burrows, C. F. C. G. Geraldes, J. J. C. Teixeira-Dias, C. G. Bazuin, D. Guillon, A. Skoulios, E. Blackmore, G. J. T. Tiddy, and D. L. Turner, Liq. Cryst. LICRE61, 215 (1986). | en_US |
dc.identifier.citedreference | C. G. Bazuin, D. Guillon, A. Skoulios, A. M. Amorim da Costa, H. D. Burrows, C. F. G. C. Geraldes, J. J. C. Teixeira-Dias, E. Blackmore, and G. J. T. Tiddy, Liq. Cryst. LICRE63, 1655 (1988). | en_US |
dc.identifier.citedreference | H. Abied, D. Guillon, A. Skoulios, P. Weber, A. M. Giroud-Godquin, and J. C. Marchon, Liq. Cryst. LICRE62, 269 (1987). | en_US |
dc.identifier.citedreference | R. C. Weast, Ed. Handbook of Chemistry and Physics, 64th ed. (CRC Press, Boca Raton, 1983). | en_US |
dc.identifier.citedreference | P. Espeau, L. Roblès, D. Mondieig, Y. Haget, M. A. Cuevas-Diarte, and H. A. J. Oonk, J. Chim. Phys. JCPBAN93, 1217 (1996). | en_US |
dc.identifier.citedreference | A. Bondi, Chem. Rev. CHREAY67, 565 (1967); Physical Properties of Molecular Crystal, Liquids and Glasses (Wiley, New York, 1968), p. 159. | en_US |
dc.identifier.citedreference | B. Wunderlich and G. Czornj, J. Polym. Sci., Polym. Phys. Ed. JPLPAY15, 1905 (1977). | en_US |
dc.identifier.citedreference | J. F. Nagle and M. Goldstein, Macromolecules MAMOBX18, 2643 (1985). | en_US |
dc.identifier.citedreference | R. C. F. Schaake, J. C. van Miltenburg, and C. G. de Kruif, J. Chem. Thermodyn. JCTDAF14, 763 (1982). | en_US |
dc.identifier.citedreference | R. C. F. Schaake, J. C. van Miltenburg, and C. G. de Kruif, J. Chem. Thermodyn. JCTDAF14, 771 (1982). | en_US |
dc.identifier.citedreference | M. Kobayashi, F. Kaneko, K. Sato, and M. Suzuki, J. Phys. Chem. JPCHAX90, 6371 (1986). | en_US |
dc.identifier.citedreference | V. Busico, P. Cernichiaro, P. Corradini, and M. Vacatello, J. Phys. Chem. JPCHAX87, 1631 (1983). | en_US |
dc.identifier.citedreference | F. Fernández-Martín, J. Am. Oil Chem. Soc. JAOCA750, 170 (1973). | en_US |
dc.identifier.citedreference | J. Barberá, C. Cativiela, J. L. Serrano, and M. M. Zurbano, Adv. Mater. ADVMEW3, 602 (1991). | en_US |
dc.identifier.citedreference | C. W. Bunn, J. Polym. Sci. JPSCAU16, 323 (1955). | en_US |
dc.identifier.citedreference | J. J. Duruz and A. R. Ubbelohde, Proc. R. Soc. London, Ser. A PRLAAZ330, 1 (1972). | en_US |
dc.identifier.citedreference | G. Klose, F. Volke, M. Hentschel, and A. Mops, Mol. Cryst. Liq. Cryst. MCLCA590, 245 (1983). | en_US |
dc.identifier.citedreference | L. Salem, J. Chem. Phys. JCPSA637, 2100 (1962). | en_US |
dc.identifier.citedreference | U. J. Ekpe and S. J. Sime, J. Chem. Soc., Faraday Trans. 1 JCFTAR72, 1144 (1976). | en_US |
dc.identifier.citedreference | V. Busico, A. Ferraro, and M. Vacatello, Mol. Cryst. Liq. Cryst. MCLCA5128, 243 (1985). | en_US |
dc.identifier.citedreference | V. Busico, P. Corradini, G. Guerra, and P. Severino, Gazz. Chim. Ital. GCITA9115, 17 (1985). | en_US |
dc.identifier.citedreference | J. Bonekamp and B. Jonas Hegemann, Mol. Cryst. Liq. Cryst. MCLCA587, 13 (1982). | en_US |
dc.identifier.citedreference | E. Baum, D. Demus, and H. Sackmann, Wiss. Z. Univ. Halle ZZZZZZ19, 37 (1970). | en_US |
dc.identifier.citedreference | M. Françon, “Progress in Microscopy,” in Modern Trends in Biological Sciences, edited by P. Alexander and Z. M. Bacq (Pergamon, New York, 1961), p. 185. | en_US |
dc.owningcollname | Physics, Department of |
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