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A thermophysical study of the melting process in alkyl chain metal n-alkanoates: The thallium (I) series
dc.contributor.authorCheda, J. A. R.en_US
dc.contributor.authorRedondo, M. I.en_US
dc.contributor.authorGarcía, M. V.en_US
dc.contributor.authorLópez De La Fuente, F. L.en_US
dc.contributor.authorFernández-Martín, F.en_US
dc.contributor.authorWestrum, Edgar F. Jr.en_US
dc.date.accessioned2010-05-06T20:51:17Z
dc.date.available2010-05-06T20:51:17Z
dc.date.issued1999-08-22en_US
dc.identifier.citationCheda, J. A. R.; Redondo, M. I.; García, M. V.; López de la Fuente, F. L.; Fernández-Martín, F.; Westrum, E. F. (1999). "A thermophysical study of the melting process in alkyl chain metal n-alkanoates: The thallium (I) series." The Journal of Chemical Physics 111(8): 3590-3598. <http://hdl.handle.net/2027.42/69602>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/69602
dc.description.abstractThe peculiar thermal behavior of the thallium(I) n-alkanoates series (consisting in several transitions between polymorphic and mesomorphic phases) in comparison with other metallic n-alkanoates series is stated. The allowance of highly accurate adiabatic heat capacity data permits a study of the CH2CH2 contributions to the lattice heat capacity curve at low temperature. Moreover, in this series an anomalous gradual enhancement of the lattice heat capacity has been interpreted from vibrational spectroscopy results as a noncooperative effect due to the internal hindered rotation of the alkyl chain (formation of gauche defects, even in the solid state). The thermodynamics of the “stepwise melting process” from the totally ordered solid at low temperature to the isotropic liquid is based on a revised lattice heat-capacity curve. This was used to evaluate the energy and entropy not only of the clear first order transitions present in the series but also of the described noncooperative effect. The CH2CH2 enthalpy and entropy contribution for this series is estimated and a comparison with the published values for other series is carried out. Moreover, the texture of the mesophases is revealed by polarized light microscopy. © 1999 American Institute of Physics.en_US
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dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleA thermophysical study of the melting process in alkyl chain metal n-alkanoates: The thallium (I) seriesen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055en_US
dc.contributor.affiliationotherDpto. Química-Física I, Fctd. CC. Químicas, Universtitaria Complutense, 28040 Madrid, Spainen_US
dc.contributor.affiliationotherInstituto del Frío (CSIC), Ciudad Universitaria, 28040 Madrid, Spainen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/69602/2/JCPSA6-111-8-3590-1.pdf
dc.identifier.doi10.1063/1.480265en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.owningcollnamePhysics, Department of


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