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Optical spectra and thermal Schottky levels in dysprosium sesquisulfide

dc.contributor.authorGruber, John B.en_US
dc.contributor.authorZandi, Bahramen_US
dc.contributor.authorJustice, Bruce H.en_US
dc.contributor.authorWestrum, Edgar F. Jr.en_US
dc.date.accessioned2010-05-06T20:58:12Z
dc.date.available2010-05-06T20:58:12Z
dc.date.issued1999-06-22en_US
dc.identifier.citationGruber, John B.; Zandi, Bahram; Justice, Bruce; Westrum, Edgar F. (1999). "Optical spectra and thermal Schottky levels in dysprosium sesquisulfide." The Journal of Chemical Physics 110(24): 12125-12130. <http://hdl.handle.net/2027.42/69677>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/69677
dc.description.abstractWe report a detailed crystal-field splitting analysis of the energy levels of Dy3+(4f9)Dy3+(4f9) in single crystals of Dy2S3Dy2S3 that have the Th3P4Th3P4 cubic defect structure. From an analysis of the temperature-dependent absorption spectra, we have identified seven of the eight crystal-field split energy (Stark) levels of the ground-state multiplet manifold, 6H15/2.6H15/2. Sixty-two experimental Stark levels from various multiplet manifolds of Dy3+Dy3+ are compared with a calculated crystal-field splitting, whose initial crystal-field parameters, Bnm,Bnm, were determined from lattice-sum calculations. The rms deviation between experimental and calculated levels is 7 cm−1. Both the experimental and calculated crystal-field splitting of the 6H15/26H15/2 manifold are compared with an assignment of Schottky levels obtained from a reassessment of heat capacity data reported earlier. Based on entropy considerations and verification of the Schottky level assignments by analyses of the optical and magnetic susceptibility data, we conclude that the anomaly observed in the heat capacity data near 3.4 K is due to antiferromagnetic ordering. © 1999 American Institute of Physics.en_US
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dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleOptical spectra and thermal Schottky levels in dysprosium sesquisulfideen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055en_US
dc.contributor.affiliationotherDepartment of Physics, San Jose State University, San Jose, California 95192-0106en_US
dc.contributor.affiliationotherArmy Research Laboratory/Sensors and Electron Devices Directorate, 2800 Powder Mill Road, Adelphi, Maryland 20783-1197en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/69677/2/JCPSA6-110-24-12125-1.pdf
dc.identifier.doi10.1063/1.479149en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
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dc.owningcollnamePhysics, Department of


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