Optical spectra and thermal Schottky levels in dysprosium sesquisulfide
dc.contributor.author | Gruber, John B. | en_US |
dc.contributor.author | Zandi, Bahram | en_US |
dc.contributor.author | Justice, Bruce H. | en_US |
dc.contributor.author | Westrum, Edgar F. Jr. | en_US |
dc.date.accessioned | 2010-05-06T20:58:12Z | |
dc.date.available | 2010-05-06T20:58:12Z | |
dc.date.issued | 1999-06-22 | en_US |
dc.identifier.citation | Gruber, John B.; Zandi, Bahram; Justice, Bruce; Westrum, Edgar F. (1999). "Optical spectra and thermal Schottky levels in dysprosium sesquisulfide." The Journal of Chemical Physics 110(24): 12125-12130. <http://hdl.handle.net/2027.42/69677> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/69677 | |
dc.description.abstract | We report a detailed crystal-field splitting analysis of the energy levels of Dy3+(4f9)Dy3+(4f9) in single crystals of Dy2S3Dy2S3 that have the Th3P4Th3P4 cubic defect structure. From an analysis of the temperature-dependent absorption spectra, we have identified seven of the eight crystal-field split energy (Stark) levels of the ground-state multiplet manifold, 6H15/2.6H15/2. Sixty-two experimental Stark levels from various multiplet manifolds of Dy3+Dy3+ are compared with a calculated crystal-field splitting, whose initial crystal-field parameters, Bnm,Bnm, were determined from lattice-sum calculations. The rms deviation between experimental and calculated levels is 7 cm−1. Both the experimental and calculated crystal-field splitting of the 6H15/26H15/2 manifold are compared with an assignment of Schottky levels obtained from a reassessment of heat capacity data reported earlier. Based on entropy considerations and verification of the Schottky level assignments by analyses of the optical and magnetic susceptibility data, we conclude that the anomaly observed in the heat capacity data near 3.4 K is due to antiferromagnetic ordering. © 1999 American Institute of Physics. | en_US |
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dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Optical spectra and thermal Schottky levels in dysprosium sesquisulfide | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055 | en_US |
dc.contributor.affiliationother | Department of Physics, San Jose State University, San Jose, California 95192-0106 | en_US |
dc.contributor.affiliationother | Army Research Laboratory/Sensors and Electron Devices Directorate, 2800 Powder Mill Road, Adelphi, Maryland 20783-1197 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/69677/2/JCPSA6-110-24-12125-1.pdf | |
dc.identifier.doi | 10.1063/1.479149 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
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dc.owningcollname | Physics, Department of |
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