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Mechanical property and physical structure changes in highly hot‐drawn polycarbonate

dc.contributor.authorDeRudder, J. L.en_US
dc.contributor.authorFilisko, Frank E.en_US
dc.date.accessioned2010-05-06T21:12:37Z
dc.date.available2010-05-06T21:12:37Z
dc.date.issued1977-10en_US
dc.identifier.citationDeRudder, J. L.; Filisko, F. E. (1977). "Mechanical property and physical structure changes in highly hot‐drawn polycarbonate." Journal of Applied Physics 48(10): 4026-4031. <http://hdl.handle.net/2027.42/69826>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/69826
dc.description.abstractThe effect of hot stretching on the structure and properties of bisphenol‐A polycarbonate was studied to determine if ordering and conformational changes occur, and their effect on the impact toughness of PC. The mechanical properties of hot‐stretched PC were found to follow the same behavior observed for enthalpy changes, which showed (1) a drop at draw ratios between 2 and 5; (2) a plateau region extending out to a draw ratio of 45; (3) a further drop at draw ratios of 57 and 62. The enthalpy decrease at a draw ratio of 62 is comparable to that found for 15% solvent‐crystallized PC; yet, wide‐angle x‐ray diffraction indicates that no crystallinity is present. Annealing of this highly hot‐drawn PC increased the enthalpy by 7.5 kJ/kg, indicating that this highly hot‐drawn PC must be in an ordered state.en_US
dc.format.extent3102 bytes
dc.format.extent460366 bytes
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dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleMechanical property and physical structure changes in highly hot‐drawn polycarbonateen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Materials and Metallurgical Engineering, Macromolecular Research Center, The University of Michigan, Ann Arbor, Michigan 48109en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/69826/2/JAPIAU-48-10-4026-1.pdf
dc.identifier.doi10.1063/1.323442en_US
dc.identifier.sourceJournal of Applied Physicsen_US
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dc.owningcollnamePhysics, Department of


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