Fractal chemical kinetics: Simulations and experiments
dc.contributor.author | Anacker, Lola W. | en_US |
dc.contributor.author | Kopelman, Raoul | en_US |
dc.date.accessioned | 2010-05-06T21:12:42Z | |
dc.date.available | 2010-05-06T21:12:42Z | |
dc.date.issued | 1984-12-20 | en_US |
dc.identifier.citation | Anacker, L. W.; Kopelman, R. (1984). "Fractal chemical kinetics: Simulations and experiments." The Journal of Chemical Physics 81(12): 6402-6403. <http://hdl.handle.net/2027.42/69827> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/69827 | |
dc.description.abstract | We relate the effective order X of the elementary binary reaction, A+A→ products, on a fractal, to the spectral dimension. For ds<2: X=1+2/ds. We regain the calsssical value (X=2) for the cubic lattice but get X=3 for the linear lattice. Supercomputer simulations (transient and steady state) and exciton fusion experiments are in quantitative agreement with the above. For percolating clusters X=2.5 and for the Sierpinski gasket X=2.45. Relevance to heterogeneous kinetics is discussed. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 171413 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Fractal chemical kinetics: Simulations and experiments | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/69827/2/JCPSA6-81-12-6402-1.pdf | |
dc.identifier.doi | 10.1063/1.447553 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
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dc.owningcollname | Physics, Department of |
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