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Force Constant of the Association Bond in the Formic and Acetic Acid Dimers
dc.contributor.authorHalford, J. O.en_US
dc.date.accessioned2010-05-06T21:17:51Z
dc.date.available2010-05-06T21:17:51Z
dc.date.issued1946-06en_US
dc.identifier.citationHalford, J. O. (1946). "Force Constant of the Association Bond in the Formic and Acetic Acid Dimers." The Journal of Chemical Physics 14(6): 395-398. <http://hdl.handle.net/2027.42/69883>en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/69883
dc.description.abstractThe entropies of the formic and acetic acid dimers are used to find a minimum value for the force constant of the association bond. With the aid of a normal coordinate treatment the probable value is found to be 4×104 dynes/cm. This agrees with a rough estimate from the heat of dimerization. A Raman band in the formic acid spectrum at 200 cm−1 may be due to the association vibrations.en_US
dc.format.extent3102 bytes
dc.format.extent252960 bytes
dc.format.mimetypetext/plain
dc.format.mimetypeapplication/pdf
dc.publisherThe American Institute of Physicsen_US
dc.rights© The American Institute of Physicsen_US
dc.titleForce Constant of the Association Bond in the Formic and Acetic Acid Dimersen_US
dc.typeArticleen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbtoplevelScienceen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michiganen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/69883/2/JCPSA6-14-6-395-1.pdf
dc.identifier.doi10.1063/1.1724158en_US
dc.identifier.sourceThe Journal of Chemical Physicsen_US
dc.identifier.citedreferenceJ. O. Halford, J. Chem. Phys. 9, 859 (1941); 10, 582 (1942).en_US
dc.identifier.citedreferenceL. Pauling and L. O. Brockway, Proc. Nat. Acad. Sci. 20, 336 (1934).en_US
dc.identifier.citedreferenceJ. Karle and L. O. Brockway, J. Am. Chem. Soc. 66, 574 (1944).en_US
dc.identifier.citedreferenceJ. T. Edsall, J. Chem. Phys. 4, 1 (1937).en_US
dc.identifier.citedreferenceK. W. F. Kohlrausch, F. Koppl, and A. Pongratz, Zeits. f. Physik. Chemie 21B, 242 (1933).en_US
dc.identifier.citedreferenceY. Morino and S. Mizushima, Sci. Pap. Inst. Phys. Chem. Research (Tokyo) 32, 33 (1937).en_US
dc.identifier.citedreferenceJ. H. Hibben, The Raman Effect and Its Chemical Applications (Reinhold Publishing Corporation, New York, 1939), p. 180.en_US
dc.owningcollnamePhysics, Department of


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