Raman Spectra, Vibrational Assignments, and Force Constants for BH3CO and BD3CO
dc.contributor.author | Taylor, Robert Cooper | en_US |
dc.date.accessioned | 2010-05-06T21:28:26Z | |
dc.date.available | 2010-05-06T21:28:26Z | |
dc.date.issued | 1957-05 | en_US |
dc.identifier.citation | Taylor, Robert Cooper (1957). "Raman Spectra, Vibrational Assignments, and Force Constants for BH3CO and BD3CO." The Journal of Chemical Physics 26(5): 1131-1135. <http://hdl.handle.net/2027.42/69997> | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/69997 | |
dc.description.abstract | Raman spectra of BH3CO and BD3CO have been obtained for the liquid state at —80°C, and a complete assignment of the sixteen fundamentals of the two molecules has been made with the help of the Teller‐Redlich product rule and a normal coordinate treatment. The calculations were carried out using the FG method of Wilson, ten symmetry force constants being required to produce a fit with a standard deviation of 0.3% from the observed fundamentals. Extension of the calculations to include the isotopic B10 molecules gave results in agreement with the data available. | en_US |
dc.format.extent | 3102 bytes | |
dc.format.extent | 415347 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.publisher | The American Institute of Physics | en_US |
dc.rights | © The American Institute of Physics | en_US |
dc.title | Raman Spectra, Vibrational Assignments, and Force Constants for BH3CO and BD3CO | en_US |
dc.type | Article | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/69997/2/JCPSA6-26-5-1131-1.pdf | |
dc.identifier.doi | 10.1063/1.1743482 | en_US |
dc.identifier.source | The Journal of Chemical Physics | en_US |
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dc.identifier.citedreference | S. M. Ferigle and A. G. Meister, J. Chem. Phys. 19, 982 (1951). | en_US |
dc.identifier.citedreference | B. L. Crawford and P. C. Cross, J. Chem. Phys. 6, 525 (1938). | en_US |
dc.identifier.citedreference | R. P. Bell and H. C. Longuet‐Higgins, Proc. Roy. Soc. (London) A183, 357 (1945). | en_US |
dc.identifier.citedreference | B. L. Crawford and J. T. Edsall, J. Chem. Phys. 7, 223 (1939). | en_US |
dc.identifier.citedreference | Unpublished datum from a complete quadratic valence force treatment based on the Raman frequencies of the borohydride and borodeuteride ions dissolved in liquid ammonia. | en_US |
dc.identifier.citedreference | F. Halvorsen, Revs. Modern Phys. 19, 87 (1947). | en_US |
dc.owningcollname | Physics, Department of |
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